The performance of an Imidazoline based commercial corrosion inhibitor on CO2 corrosion of mild steel was investigated in a Cl- containing solution employing linear polarization resistance (LPR), potentiodynamic polarization and monitoring corrosion potential techniques. Experimental results showed that an increase of the commercial inhibitor concentration up to 500 ppm increases the RP value a...

the equilibrium solubility data of co2 in the various aqueous blends of triisopropanolamine (tipa) + monoethanolamine (mea) with the total alkanolamine concentration of 2 mole / dm3 were measured at the temperatures of 30, 40, 50, 60 and 70 oc and co2 partial pressures below 100 kpa. the experiments were done in an atmospheric gas absorption system and the amount of absorbed co2 was measured wi...

A mechanistic model of uniform carbon dioxide (CO2) corrosion is presented that covers the following: electrochemical reactions at the steel surface, diffusion of species between the metal surface and the bulk including diffusion through porous surface films, migration due to establishment of potential gradients, and homogenous chemical reactions including precipitation of surface films. The mo...

The aim of this research was to investigate the influence of metallurgy on the corrosion behaviour of separate weld zone (WZ) and parent plate (PP) regions of X65 pipeline steel in a solution of deionised water saturated with CO2, at two different temperatures (55 °C and 80 °C) and at initial pH~4.0. In addition, a non-electrochemical immersion experiment was also performed at 80 °C in CO2, on ...

The U.S. Department of Energy (DOE) Office of Fossil Energy is intensely promoting research and development of oxy-fuel combustion systems that employ oxygen, instead of air, for burning the fuel. The resulting flue gas primarily consists of H2O and CO2 that facilitates sequestration of CO2 or use it in a turbine to generate electricity, thereby leading to reduction in CO2 emissions. Also, as t...

In carbon dioxide (CO2) corrosion of steels, the bicarbonate ion (HCO3) is simultaneously the buffer for carbonic acid (H2CO3), the source of iron carbonate (FeCO3) precipitation, and the product of the cathodic reaction. In addition to spatial separation of the production of Fe2+ and HCO3, galvanic coupling between the steel and cementite (Fe3C) layers is the principal cause of internal acidif...

Glass cell experiments were conducted to investigate kinetics of iron sulfide and mixed iron sulfide/carbonate scale precipitation in CO2/H2S corrosion. Weight gain/loss (WGL) method was used to investigate the scale formation using X65 carbon steel as substrates. Scanning Electron Microscopy (SEM/EDS), X-ray Diffraction methodology (XRD), X-ray Photoelectron Spectroscopy (XPS), and Electron Pr...

A model has been developed for calculating the rates of general corrosion of carbon steel and 13%Cr steel in aqueous systems containing carbon dioxide, hydrogen sulfide and other components. The model combines a comprehensive thermodynamic speciation module with electrochemical computations based on the mixed-potential theory. The electrochemical calculations recognize the effects of various pa...

Corrosion, from long time before was a greatest problem in oil and gas industry and experts have always tried to combat this major problem. This has been given to the corrosion and inspection in oil and gas industry. Corrosion in oil and gas wells has the electrochemical mechanism, When the system reaches a temperature below the dew point, moisture is converted to liquid and many droplets occur...