Energy-efficient CH4-CO2 valorization to fuels and chemicals presents an urgent need considering the great variety of methane sources removal greenhouse gases. In present work, microwave-assisted dry reforming methane, DRM, has been carried out in a custom-designed rectangular mono-mode microwave applicator over several catalyst-support combinations, i.e., Pt/C, Ni/Al2O3, mechanical mixture Ni/...

Hydrogen production is critical to many modern chemical processes – ammonia synthesis, petroleum refining, direct reduction of iron, and more. Conventional approaches hydrogen manufacture include steam methane reforming autothermal reforming, which today account for the lion's share generation. Without CO2 capture, these emit about 8.7 kg each H2 produced. In this study, a molten carbonate fuel...

The intrinsic kinetics and diffusion behaviour of methane steam reforming have been investigated in this work. Measurements of effective diffusivities of the gases present in methane steam reforming have been carried out by using the steady-state technique over wide ranges of temperature and pressure in a modified Wicke-Kallenbach (W-K) type diffusion apparatus. The effects of diffusion limitat...

Transitioning to lower carbon energy and environment sustainability requires a reduction in greenhouse gases such as dioxide (CO2) methane (CH4) that contribute global warming. One of the most actively studied rare earth metal catalysts is cerium oxide (CeO2) which produces remarkable improvements dry reforming methane. This paper reviews management CO2 emissions recent advent trends bimetallic...

Article history: Received 11 October 2015 Received in revised form 2 December 2015 Accepted 15 December 2015 Available online 17 December 2015 The dry reforming of methane (DRM) utilizes carbon dioxide (CO2) as the oxidizing agent in order to produce synthesis gas. Catalyst deactivation via coking, oxidation, and sintering has stymied the industrialization of catalysts for the DRM. Here, we uti...

Two fluidized bed membrane reactor concepts for hydrogen production via autothermal reforming of methane with integrated CO2 capture are proposed. Ultrapure hydrogen is obtained via hydrogen perm-selective Pd-based membranes, while the required reaction energy is supplied by oxidizing part of the CH4 in situ in the methane combustion configuration or by combusting part of the permeated H2 in th...

In this work it is analyzed the performance of an iron waste material as oxygen carrier for a chemical-looping combustion (CLC) system. CLC is a novel combustion technology with the benefit of inherent CO2 separation that can be used as a source of energy for the methane steam reforming process (SR). The tail gas from the PSA unit is used as fuel in the CLC system. The oxygen carrier behaviour ...

The CO2 (dry) reforming of hydrocarbons offers an opportunity to convert greenhouse gases into synthesis gas, which can further transform various valued products. Here we explore the influence Rh particle size and support on propane methane. To that end, nanoparticles with controlled sizes varying from 1.6-8.0 nm were synthesized following a polyol reduction method then dispersed three differen...