The incorporation of cobalt into low molecular mass nitrile hydratase (L-NHase) of Rhodococcus rhodochrous J1 has been found to depend on the alpha-subunit exchange between cobalt-free L-NHase (apo-L-NHase lacking oxidized cysteine residues) and its cobalt-containing mediator (holo-NhlAE containing Cys-SO(2)(-) and Cys-SO(-) metal ligands), this novel mode of post-translational maturation havin...

The structural and electrical properties of polyaniline-cobalt sulphate nanocomposite prepared by chemical method.Polyaniline-cobalt sulphate nanocomposites were synthesized by the cobalt sulphate and ammonium persulphate and aniline.This paper reports on chemical technique using for synthesis of cobalt nanoparticles in the composite bridge is aniline. Electrical conductivity of polyaniline wit...

The structural and electrical properties of polyaniline-cobalt sulphate nanocomposite prepared by chemical method.Polyaniline-cobalt sulphate nanocomposites were synthesized by the cobalt sulphate and ammonium persulphate and aniline.This paper reports on chemical technique using for synthesis of cobalt nanoparticles in the composite bridge is aniline. Electrical conductivity of polyaniline wit...

The coordination chemistries of the tetradentate N2O2-type ligands N-(2-pyridylmethyl)iminodiethanol (H2pmide) and N-(2-pyridylmethyl)iminodiisopropanol (H2pmidip) have been investigated with nickel(ii) and cobalt(ii/iii) ions. Three novel complexes prepared and characterized are [(Hpmide)2Ni3(CH3COO)4] (1), [(Hpmide)2Co3(CH3COO)4] (2), and [(pmidip)2Co3(CH3COO)4] (3). In 1 and 2, two terminal ...

Since the demonstration by Waltner and Waltner (1) that cobalt will produce a polycythemia in rats, this effect has been produced in various other laboratory animals and human beings. However, the mechanism by which cobalt produces erythroid hyperplasia of the bone marrow remains obscure. This unique action of cobalt continues to be of interest because of its importance in leading to a better u...

Abstract: Cobalt is a very important metal which is widely applied in various critical areas, however, it is difficult to recover cobalt from minerals since there is a lack of independent cobalt deposits in nature. This work is to provide a complete process to recover cobalt from cobalt tailings using the moderately thermophilic bioleaching technology and selective sequential extraction. It is ...

[1] The geochemistry of cobalt in the Peru upwelling region is dominated by its importance as a micronutrient. A large and previously undocumented flux of labile cobalt behaved as a micronutrient with correlations with major nutrients (nitrate, phosphate; r = 0.90, 0.96) until depleted to 50 pM of strongly complexed cobalt. Co:P utilization ratios were an order of magnitude higher than in the N...

Cobalt has been a recognized allergen capable of causing contact dermatitis for decades. Why, therefore, has it been named 2016 ‘‘Allergen of the Year’’? Simply put, new information has come to light in the last few years regarding potential sources of exposure to this metallic substance. In addition to reviewing some background on our previous understanding of cobalt exposures, this article wi...

Cobalt pi-complexes, previously described in the literature and specially synthesized and characterized in this work, were used as catalysts in homogeneous oxidation of organic compounds with peroxides. These complexes contain pi-butadienyl and pi-cyclopentadienyl ligands: [(tetramethylcyclobutadiene)(benzene)cobalt] hexafluorophosphate, [(C₄Me₄)Co(C₆H₆)]PF₆ (1); diiodo(carbonyl)(pentamethylcyc...