A novel thiosemicarbazone from 2-acetonaphthone (represented as acnTSC) has been synthesized and its basic coordination chemistry with zinc(II), cobalt(II), and copper(II) explored. The complexes were characterized by elemental analysis and various spectroscopic techniques and are best formulated as [M(acnTSC)(2)Cl(2)] with the metal likely in an octahedral environment. The anticancer activity ...

Additives per kg: Vitamins – E672 vitamin A 5,000 IU; vitamin C 50 mg; E671 vitamin D3 250 IU; 3a700 vitamin E 25 mg. Trace elements E5 Manganese (manganese chelate of glycine hydrate) 7,000 mg; E6 Zinc (zinc chelate of glycine hydrate) 6,500 mg; E1 Iron (iron chelate glycine hydrate) 6,000mg; E4 Copper (copper chelate of glycine hydrate) 4,000 mg; E2 Iodine (potassium iodide) 5 mg; E8 Selenium...

Cobalt zinc oxide catalysts have been prepared by anti-solvent precipitation in supercritical CO2 and investigated for CO hydrogenation. Here we show how the textural and catalytic properties of the catalyst can be tailored by the addition of water to the initial solution of cobalt and zinc acetates in methanol. Characterization of the catalysts by powder X-ray diffraction, infra-red and Raman ...

Single metal-organic frameworks (MOFs), constructed from the coordination between one-fold metal ions and organic linkers, show limited functionalities when used as precursors for nanoporous carbon materials. Herein, we propose to merge the advantages of zinc and cobalt metals ions into one single MOF crystal (i.e., bimetallic MOFs). The organic linkers that coordinate with cobalt ions tend to ...

Escherichia coli alkaline phosphatase exhibits maximal activity when Zn(2+) fills the M1 and M2 metal sites and Mg(2+) fills the M3 metal site. When other metals replace the zinc and magnesium, the catalytic efficiency is reduced by more than 5000-fold. Alkaline phosphatases from organisms such as Thermotoga maritima and Bacillus subtilis require cobalt for maximal activity and function poorly ...

More than 80% of the world’s production of zinc from its concentrate is obtained by the roastleach-electrowin hydrometallurgical process. In the roast-leach process, very pure zinc sulphate solution must be prepared for zinc electrowinning, therefore, the purification process is one of the most important unit processes in zinc hydrometallurgy. The conventional methods for the zinc solution puri...

magnetic nanoparticles attracted a great deal of attention in the medical applications due to their unique properties. the most exceptional property of magnetic particles is their response to a magnetic force, and this property has been utilized in applications such as drug targeting, bioseparation, contrast agents in magnetic resonance imaging (mri) and heating mediators for cancer therapy. in...

Aim. To determine trace element status and aetiologic factors for development of trace elements deficiencies in children with iron-deficiency anaemia (IDA) aged 0 to 3 years. Contingent and Methods. 30 patients of the University Hospital, Pleven, Bulgaria-I group; 48 patients of the Sumy Regional Child's Clinical Hospital, Sumy, Ukraine-II group; 25 healthy controls were investigated. Serum con...

Metal replacement studies were used to investigate the metal requirement of a bacterially expressed polypeptide encoding the zinc finger DNA binding domain of the estrogen receptor. Apopolypeptide was generated by dialysis of native polypeptide against low-pH buffer under reducing conditions. Specific DNA binding can be restored by refolding the apopolypeptide in the presence of ionic zinc, cad...

Lead, copper, cobalt, nickel, iron and zinc ions form monocitrate complexes (negative charge) in citrate solution which is absorbed on the citrate form of anion-exchange resins (citrate as counter ion) y exchange of citrate ion with citrate complexes. These are subsequently recovered from the resin by 0.5M ammonium citrate eluent at pH 2.0. Under optimized conditions, quantitative recovery ...