Sulfur dioxide (SO2), a typical gaseous compound found in the atmosphere, corrodes metals, particularly outdoors. When SO2 adsorbs on the surface electrolyte, it easily dissolves, resulting in the formation of protons (H+) and bisulfite ions (HSO3). The former reduces the pH of the surface electrolyte, which promotes metal dissolution. Silver and copper are commonly used in the electronic compo...

The optical frequency doubling properties of silver, copper, and platinum nanoparticles in aqueous solution are studied via hyper-Rayleigh scattering (HRS) spectroscopy. Substantial HRS responses are observed for silver and copper particles. The response is attributed to enhancement due to resonance of the nonlinearly scattered light with the particles’ surface plasmon absorption band. Platinum...

We demonstrate aqueous phase biosynthesis of phase-pure metallic copper nanoparticles (CuNPs) using a silver resistant bacterium Morganella morganii. This is particularly important considering that there has been no report that demonstrates biosynthesis and stabilization of pure copper nanoparticles in the aqueous phase. Electrochemical analysis of bacterial cells exposed to Cu(2+) ions provide...

Dispersion relations of the s–p derived surface state on (111) surfaces of silver and copper have been measured using low-temperature scanning tunneling microscopy and spectroscopy. For silver as well as for copper we find a significant deviation from a parabolic dispersion characteristic of free-electron-like systems. A simple tight-binding model accounts for the trends in the measured dispers...

The subject of catalysis by coinage metals (copper, silver, and gold) comes up increasingly day-by-day. This Special Issue aims to cover the numerous aspects of the use of these metals as catalysts for several reactions. It deals with synthesis and characterization of copper, silver and gold based catalysis, their characterization and use, both for heterogeneous and homogeneous catalysis, and s...

A single-step, low-temperature (<210 degrees C) and -pressure (<20 atm) hydrothermal method has been developed to synthesize a series of silver delafossites, AgBO2 (B = Al, Ga, Sc, and In). Experimental and computational studies were performed to understand the optical and electric properties of these silver delafossites, including the first in-depth study of AgAlO2 and AgScO2. Their properties...

Materials exhibiting high ionic conductivities in the solid state at room temperature have mainly been found in silver ion conductors based on silver iodide and in copper ion conductors which are based on cuprous halide. Silver iodide and cuprous halide show low ionic conductivities at room temperature, while they are high conductivity solids at relatively higher temperatures. In order to obtai...

The efficacy of copper and silver ions, in combination with low levels of free chlorine (FC), was evaluated for the disinfection of hepatitis A virus (HAV), human rotavirus (HRV), human adenovirus, and poliovirus (PV) in water. HAV and HRV showed little inactivation in all conditions. PV showed more than a 4 loglo titer reduction in the presence of copper and silver combined with 0.5 mg of FC p...

Underwater plasma discharge is used for surface activation of polypropylene nonwoven fabrics with subsequent immobilisation of silver or copper. Plasma generated at atmospheric pressure is preferred as this is a low cost and environmental considerate technique in comparison with other techniques. At the same time, the antibacterial properties of silver and copper are well known. The underwater ...

Ionic copper- or silver-doped dense silica rods have been prepared by sintering sol-gel porous silica xerogels doped with ionic precursors. The precipitation of Cu or Ag nanoparticles was achieved by heat treatment under hydrogen followed by annealing under air atmosphere. The surface plasmon resonance bands of copper and silver nanoparticles have been clearly observed in the absorption spectra...