hydrous manganese dioxide nanoclusters are prepared by the oxidation of manganese (ii) ions with ammonium persulfate and used as a new sorbent for ag+ ion removal from aqueous medium. the synthesized compound is characterized using scanning electron microscopy, dynamic light scattering, energy dispersive analysis of x-rays, x-ray diffraction and bet surface measurements. scanning electron micro...

The nonlinear optical properties and the role of the surface-plasmon resonance (SPR) on optical limiting (OL) properties of Ag–Cu nanoclusters co-doped in SiO2 matrix prepared using the sol-gel technique with a Cu/Ag molar ratio of 1, 2 and 3, respectively, are presented. The studies were made using the second harmonic of high-power nanosecond and picosecond Nd:YAG lasers. These films show a se...

Few-atom noble metal nanoclusters have attracted a lot of interest due to their potential applications in biosensor development, imaging and catalysis. DNA-templated silver nanoclusters (AgNCs) are of particular interest as different emission colors can be obtained by changing the DNA sequence. A popular analytical application is fluorescence quenching by Hg(2+), where d(10)-d(10) metallophilic...

The development of functional copper nanoclusters (Cu NCs) is becoming increasingly widespread in consumer technologies due to their applications in cellular imaging and catalysis. Herein, we report a simple protein-directed synthesis of stable, water-soluble and fluorescent Cu NCs, using BSA as the stabilising agent. Meanwhile, in this study, hydrazine hydrate (N₂H₄·2H₂O) was used as the reduc...

comparison of the effects of two substrates and additives on pulse current electrodeposition of au nanoparticles showed that using indium-tin oxide instead of cu and cysteine instead of potassium iodide can improve morphology, current efficiency, photocatalytic effect and increase the number of nanocrystals. the examinations using the field-emission scanning-electron-microscope (fe-sem) showed ...

DFT+U calculations of the structure of CeO2(111)-supported Aubased bimetallic nanoclusters (NCs) show that a strong support−metal interaction induces a preferential segregation of the more reactive element to the NC−CeO2 perimeter, generating an interface with the Au component. We studied several Au -based bimetallic NCs (Au-X, X: Ag, Cu, Pd, Pt, Rh, and Ru) and found that (Au− Cu)/CeO2 is opti...

We explore the dynamics of low temperature interfacial water nanoclusters on Cu(111) by femtosecond-laser excitation, scanning tunneling microscopy and density functional theory. Laser illumination is used to induce single molecules to diffuse within water clusters and across the surface, breaking and reforming hydrogen bonds. A linear diffusion probability with laser fluence is observed up to ...