BACKGROUND, AIM, AND SCOPE Diffusive gradients in thin films (DGT) have been recognized as a suitable tool to assess in situ metal bioavailability in soils. Mine tailings have some singular characteristics such as high heavy-metal concentrations, low pH, or absence of water retention capacity that may compromise the correct application of this technique whose applicability is known to be pH dep...

In the medical computer tomography (CT) field, total variation (TV), which is the 1  -norm of the discrete gradient transform (DGT), is widely used as regularization based on the comprehensive sensing (CS) theory. To overcome the TV model’s disadvantageous tendency of uniformly penalize the image gradient and over smooth the low-contrast structures, an iterative algorithm based on the 0  -nor...

Diffusive gradients in thin films (DGT) devices were used to investigate the temporal and spatial changes in vanadium (V) speciation in the Churchill estuary system (Manitoba). Thirty-six DGT sets and 95 discrete water samples were collected at 8 river and 3 estuary sites during spring freshet and summer base flow. Dissolved V concentration in the Churchill River at summer base flow was approxi...

Diffusive gradient in thin-films (DGT) technology was used to monitor bio-available metals and the tool was developed for risk-based pollution assessment and liability apportionment in the Witwatersrand Goldfields, South Africa, where there is widespread mine-related pollution. DGT technology is a passive sampling technique whereby metal species are selectively diffused from polluted water thro...

Passive water sampling has several advantages over active methods; it provides time-integrated data, can save on time and cost compared to active methods, and yield high spatial resolution data through co-deployment of simple, cheap units. However, one problem with many sampler designs in current use is that their uptake rates for trace substances of interest are flow-rate dependent, thereby re...

Ethylene synthesis in vegetative tissues is thought to be controlled by indoleacetic acid (IAA). However, ethylene synthesis in the diageotropica (dgt) mutant of tomato (Lycopersicon esculentum Mill.) was much less sensitive to IAA than in the normal variety (VFN8). Yet, mechanical wounding stimulated ethylene production by the mutant. The dgt tomato provides an opportunity to study the regulat...

Tomato (Lycopersicon esculentum Mill.) plants heterozygous for the diageotropica (dgt) mutation exhibit a unique phenotype, termed ;mottled.' Unlike dgt, mottled individuals grow upright, exhibit normal root branching, and produce normal levels of ethylene in response to applied auxin. Leaves of mottled plants are deformed and reduced in size and are characterized by a mottled appearance on the...

Organotins present a toxicological risk to biota in the aquatic environment. Understanding the behaviour of these compounds in sediment is challenging, with sophisticated analytical techniques required for their measurement. We investigated the use of silica-bound sorbents for diffusive gradients in thin-films (DGT) adsorption gels to pre-concentrate five organotins (monobutlytin (MBT), dibutyl...