The inverse sandwich Ca-C8H8-Ca is predicted to be an open-shell singlet state. Since the C8H8 ligand prevents the spin-up and spin-down electrons of different calcium atoms from forming Ca-Ca bonds, the spin-coupling electrons lead to a singlet diradical character. The metal-ligand interaction contributes to the stability of Ca-C8H8-Ca against dissociation and isomerization. For the coordinati...

For the last decade, dimethyl ether (DME) has been considered a promising alternative fuel for direct fuel cells because of several advantages over methanol. In this work, PtRu catalysts with a wide range of Pt-to-Ru ratios were screened for the direct DME fuel cell (DDMEFC) performance for the first time. Overall, Pt50Ru50 performs best in the high and middle voltage ranges, whereas Pt80Ru20 p...

Biomass from Oil Palm Empty Fruit Bunch (OPEFB) has the potential to be used as feedstock for bio-Dimethyl Ether (bio-DME) production through gasification process. Bio-DME replace liquified petroleum gas (LPG) and biodiesel it similar characteristics both fuels. Therefore, this study was aimed evaluate previous research on OPEFB-based bio-DME its sustainability, identify existing gaps in formul...

Mordenite (H-MOR) catalysts were synthesized by a hydrothermal method, and silver-modified mordenite (Ag-MOR) prepared ion exchange with AgNO3 at different concentrations. The performance of these in the carbonylation dimethyl ether (DME) to methyl acetate (MA) was also evaluated. characterized Ar adsorption/desorption, XRD, ICP-AES, SEM, HRTEM, 27Al NMR, H2-TPR, NH3-TPD, Py-IR, CO-TPD. Accordi...

Recently, dimethyl ether (DME) has been paid much attention as a clean fuel. DME has many advantages as a substitute for liquefied petroleum gas (LPG). Sulfur oxides (SOx), and particulate matters (PM) are not produced at the combustion. Infrastructures and equipments for LPG can be used with slight improvements, because physical properties of DME are similar to those of light hydrocarbons, pro...

hydrogen was produced by steam reforming of dimethyl ether (dme) using a physical mixture of commercial hzsm-5 zeolite (for dme hydrolyzing) and cu/zno/al2o3 (for methanol steam reforming) as a catalyst in a fixed bed reactor. the experiments were performed at atmospheric pressure and in a temperature range from 270 to 310 °c. the effects of feed temperature and gas hourly space velocity (ghsv)...

Dimethyl Ether (DME) has been attracting attention as an alternative fuel for diesel engines because it can be produced from various feed stocks and does not create smoke. On the other hand, a DME truck require a large volume fuel tank in order to obtain the running distance equivalent to diesel trucks due to the lower energy content per unit volume of DME, and un-burned gas and fuel consumptio...

Embryonic X-ray amorphous semi-formed MFI-type zeolite units mixed with the Cu–Zn–Al catalyst have been used for direct synthesis of dimethyl ether (DME) from syngas. The hybrid embryonic (EZ) particle size 5 nm has demonstrated superior performance in terms activity, selectivity, and stability compared to crystalline ZSM-5 counterpart aluminosilicate material. FTIR pyridine adsorption uncovere...

Dimethyl ether (DME)/C1-C4 alkane mixtures are ideal fuel for homogeneous charge compression ignition (HCCI) engines. The comparison of delay and multi-stage DME/C1-C4 can provide theoretical guidance expanding the load range controlling time DME HCCI However, interaction mechanism between C1-C4 under engine relevant high-pressure low-temperature conditions remains to be revealed, especially co...

The industrial production of dimethyl ether (DME) is now about 10,000 ton/year in Japan, and DME has been mainly used as an aerosol propellant. Recently, DME can be directly synthesized from water gas, carbon monoxide and hydrogen, by use of a new type catalyst dispersed in fluids. So, a large amount of DME will be supplied in future. Considering the molecular structure, the physical properties...