The behavior of doped and undoped nano-particles find a great deal of application in opto-electronic and semiconductor devices, so ZnS nano-crystals were grown into poly-vinyl alcohol matrix by chemical route at different wt percentage. Optical properties of both undoped and doped with ZnS nano-crystalline compounds were studied. The nano structure was characterized with the help of X-ray diffr...

Heterostructures involving ZnS/GaN show promise for the injection of holes from p-GaN into n-ZnS. Utilizing knowledge obtained from ZnS phosphor technology, this combination could result in a new type of multi-color electroluminescent display. Further, this combination provides a very interesting interface. Both ZnS and GaN are very ionic materials. Hence, it is desirable that the interface wil...

Aqueous leaf extract of Plectranthus barbatus was used, for the first time, preparation (2, 6 mol%) silver (Ag)-doped zinc sulfide nanoparticles (ZnS NPs), acting as a stabilizing and capping agent NPs’ production. The obtained metal oxides were characterized by FTIR, UV-visible, XRD, SEM methods. results revealed that 0.02 0.06% Ag-doped ZnS had optical bandgaps 3.20 3.03 eV. XRD evinced cryst...

ZnS:Cu/Poly(vinyl alcohol) (PVA) composite nanofibers have been successfully prepared by electrospinning technique. The formation of ZnS: Cu/PVA nanofibers were carried out by reacting H2S with Zn(AC)2:Cu/PVA nanofibers, which were electrospun from the mixture aqueous solution of Zn(Ac)2, Cu(Ac)2 and PVA. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray-diffr...

CuInS2 (CIS) quantum dots (QDs) have tunable photoluminescence (PL) behaviors in the visible and near infrared spectral range with markedly lower toxicity than the cadmium-based counterparts, making them very promising applications in light emitting and solar harvesting. However, there still remain material- and fabrication- related obstacles in realizing the high-performance CIS-based QDs with...

Transition metal doped semiconductor nanocrystals (d-dots) possess fundamentally different emission properties upon photo- or electroexcitation, which render them as unique emitters for special applications. However, in comparison with intrinsic semiconductor nanocrystals, the potential of d-dots has been barely realized, because many of their unique emission properties mostly rely on precise c...

Nanosized photocatalysts have been shown to be important to many modern photocatalytic reactions. Control of the microstructure of the nanocrystals enables regulation of their optical properties and enhancement of specific reactions. Here, Cu(2+)-doped ZnS nanosphere photocatalysts with hierarchical nanostructures and controllable sizes were synthesized via a facile wet-chemical reaction. We de...

We describe two example pilot efforts to help define new thermoluminescent dosimeter media. The first concerns ZnS:Mn nanophosphors, prepared by chemical precipitation using zinc and sodium sulfate, doped with manganese sulfate at concentrations varying from 1 to 3mol. The second concerns chemical vapor deposited diamond, produced as a thin film or as amorphous carbon on a single-crystal silico...

A new strategy toward controllable release of NO for therapeutic purpose is described. Mn(2+)-doped ZnS quantum dots with NIR-II to visible upconversion properties were encapsulated by chitosan, with which photochemical NO precursors were conjugated to generate nanostructured materials capable of releasing NO under NIR-II irradiation.