UNLABELLED We grew silicon nanowires (SiNWs) by a vapor-liquid-solid (VLS) mechanism using metal catalysts of gold (Au), titanium (Ti), manganese (Mn), and iron (Fe) under a high flow rate of hydrogen (H2). This combination of catalyst types and high gas flow rate revealed the potential for growing various SiNWs, including kinked SiNWs (with Au), ultra-thin SiNWs having diameters about 5 nm (wi...

1. Materials synthesis and characterization Catalyst synthesis: Commercially available TiO 2 , with the particle size ranging from 50 to 150 nm and in the B.E.T. surface area from 50 to 100 m 2 /g, was first treated in 0.5 M HCl solution for 24 hours to remove impurities. In a typical approach to the synthesis of the PANI-Fe-TiO 2 catalyst, 2.0 mL aniline was first dispersed in 0.5 M HCl soluti...

the kinetic of fischer-tropsch synthesis over a co-precipitated fe-ce catalyst was investigated in a fixed bed micro reactor. experimental conditions were varied as follow: reaction pressure 1-15bar, h¬¬¬2/co feed ratio of 1-3 and space velocity of 3600-5400 h-1 at the temperature range of 270-310°c. 4 models according to the langmuir-hinshelwood-hougen-watson (lhhw) type rate equation were der...

This study focuses on the manufacture of carbon nanotubes using the arc discharge method. Several independent variables were changed, such as the current (80 and 100 A), an atmosphere of open air or argon and the catalyst (no catalyst, Fe or a mixture of Fe/Co,Ni). Only one set of parameters yielded MWNTs, involving Fe as the catalyst and an open air atmosphere. I. INTRODUCTION There has been i...

The addition of phenols to aryl-substituted alkynes to form 1,1-diarylalkenes was carried out by using the Fe-Al-MCM-41 catalyst. The catalyst showed remarkable improvement in time and yield in comparison to other solid catalysts. The heterogeneous catalyst can be reused at least three times without a significant loss in activity.

A careful comparison was performed between Cu and Fe as catalysts for the growth of horizontally aligned ultralong single-walled carbon nanotube (SWNT) arrays on SiOx/Si substrates, and the mechanism of the difference was discussed. Cleaner and straighter SWNTs with smaller diameters and narrower size distribution were obtained using Cu as catalyst. It was also found that the SWNTs always grew ...

We discuss growth of high-quality carbon nanotube (CNT) films on bare and microstructured silicon substrates by atmospheric pressure thermal chemical vapor deposition (CVD), from a Mo/Fe/Al2O3 catalyst film deposited by entirely electron beam evaporation. High-density films having a tangled morphology and a Raman G/D ratio of at least 20 are grown over a temperature range of 750–900 C. H2 is ne...

Herein, a ternary nanocomposite with TiO2 nanoparticles anchored on reduced graphene oxide (rGO)-encapsulated Fe3O4 spheres (Fe3O4@rGO@TiO2) is presented as a high efficient heterogeneous catalyst for photo-Fenton degradation of recalcitrant pollutants under neutral pH. Fe3O4@rGO@TiO2 was synthesized by depositing TiO2 nanoparticles on the surface of the Fe3O4 spheres wrapped by graphene oxide ...

For the first time, a new generation of innovative non-platinum group metal catalysts based on iron and aminoantipyrine as precursor (Fe-AAPyr) has been utilized in a membraneless single-chamber microbial fuel cell (SCMFC) running on wastewater. Fe-AAPyr was used as an oxygen reduction catalyst in a passive gas-diffusion cathode and implemented in SCMFC design. This catalyst demonstrated better...

Producing clean hydrogen from renewable resources will reduce our dependence on using fossil fuels towards a green and sustainable future. Biomass gasification is regarded as a promising technology for hydrogen production. In this work, low cost Ni-based catalyst was applied in a two-stage fixed bed reaction system. Fe was added into Ni-Al catalyst(80mol.% Al) by co-precipitation method with va...