نتایج جستجو برای: functional sba 15

تعداد نتایج: 1056397  

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه صنعتی اصفهان - دانشکده مهندسی شیمی 1394

برای بررسی توانایی tio2 در تخریب ساختار فنل از ماده فعال سطحی پلورونیک پی-123، پلورونیک اف-127 و سی تب استفاده شد. همچنین کاتالیست نوری m-tio2 ساخته و اثر آن بر تخریب ساختار فنل در آب بررسی شد. در قسمت دیگر از پایه sba-15 استفاده و کاتالیست ti-sba-15 ساخته و اثر آن بر تخریب فنل بررسی شد.

Journal: :Chemical communications 2012
Guofu Zhang Yong Wang Xin Wen Chengrong Ding Ying Li

A novel SBA-15 supported catalyst PdL(n)@SBA-15 containing a 2-pyridyl-1,2,3-triazole ligand framework was prepared via a "click" route, in which the click-triazole acted as both a stable linker and a good chelator. The catalyst was characterized and applied for the aerobic oxidation of alcohols, and the product was obtained in up to 98% yield.

2014
Mehdi Esmaeili Bidhendi Gholam Reza Nabi Bidhendi Nasser Mehrdadi Hamid Rashedi

BACKGROUND Removal of mercury from aqueous environment has been highly regarded in recent years and different methods have been tested for this purpose. One of the most effective ways for mercury ions (Hg(+2)) removal is the use of modified nano porous compounds. Hence, in this work a new physical modification of mesoporous silica (SBA-15) with 1, 3, 5 (Trithiane) as modifier ligand and its app...

2017
Chenghong Sun Jinhua Wang Jiaojiao Huang Dandan Yao Chong-Zhi Wang Lei Zhang Shuying Hou Lina Chen Chun-Su Yuan

The feasible, reliable and selective multi-template molecularly imprinted polymers (MT-MIPs) based on SBA-15 (SBA-15@MT-MIPs) for the selective separation and determination of the trace level of ginsenoside Rb1 (Rb1), ginsenoside Rg1 (Rg1) and notoginsenoside R1 (R1) simultaneously from biological samples were developed. The polymers were constructed by SBA-15 as support, Rb1, Rg1, R1 as multi-...

2015
Honglue Tan Shengbing Yang Pengyi Dai Wuyin Li Bing Yue

As a commonly used implant material, calcium sulfate cement (CSC), has some shortcomings, including low compressive strength, weak osteoinduction capability, and rapid degradation. In this study, silica-based mesoporous materials such as SBA-15 were synthesized and combined with CSC to prepare CSC/SBA-15 composites. The properties of SBA-15 were characterized by X-ray diffraction, transmission ...

Journal: :Chemical communications 2009
Lingli Ni Ji Ni Yuan Lv Ping Yang Yong Cao

Decatungstate W(10)O(32)(4-) heterogenized on a novel hydrophobically-organomodified SBA-15 was proven an efficient, green and reusable catalyst for photooxygenation by oxygen of a range of aryl alkanes to the corresponding ketones under mild conditions.

2014
Amaury Pérez-Verdejo Alvaro Sampieri Heriberto Pfeiffer Mayra Ruiz-Reyes Juana-Deisy Santamaría Geolar Fetter

This work presents two easy ways for preparing nanostructured mesoporous composites by interconnecting and combining SBA-15 with mixed oxides derived from a calcined Mg-Al hydrotalcite. Two different Mg-Al hydrotalcite addition procedures were implemented, either after or during the SBA-15 synthesis (in situ method). The first procedure, i.e., the post-synthesis method, produces a composite mat...

2013
Rafael Huirache-Acuña Rufino Nava Carmen L. Peza-Ledesma Javier Lara-Romero Gabriel Alonso-Núñez Barbara Pawelec Eric M. Rivera-Muñoz

SBA-15 is an interesting mesoporous silica material having highly ordered nanopores and a large surface area, which is widely employed as catalyst supports, absorbents, drug delivery materials, etc. Since it has a lack of functionality, heteroatoms and organic functional groups have been incorporated by direct or post-synthesis methods in order to modify their functionality. The aim of this art...

Journal: :Chemical communications 2007
Ankur Bordoloi Ajayan Vinu S B Halligudi

Tungsten oxide nanoclusters supported highly ordered mesoporous SBA-15 material has been successfully synthesized in a single step using a non-ionic surfactant as a template and used for the selective oxidation of sulfur compounds, giving excellent yields at room temperature with exceptional catalyst recyclability.

Journal: :Molecules 2014
Liliana Giraldo Marlon Bastidas-Barranco Juan Carlos Moreno-Piraján

In the present work, mesoporous SBA-15 and SBA-16 were synthesised using classical methods, and their physicochemical properties were investigated by X-ray diffraction (XRD), FTIR, TEM and N2 adsorption-desorption. Rhodium (Rh, 1 wt %) was loaded on the mesoporous SBA-15 and SBA-16 by an impregnation method. The Rh surface coverage, dispersion and crystallite size were determined by room temper...

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