نتایج جستجو برای: geometrical isomerism

تعداد نتایج: 38939  

2014
Mi-Young Lee Hye-Sung Won Jae-Yoon Shim Pil-Ryang Lee Byong Sop Lee Ellen Ai-Rhan Kim Young-Hwue Kim Jeong-Jun Park Tae-Jin Yun Ahm Kim

OBJECTIVE To report our experiences in the prenatal diagnosis of atrial isomerism and postnatal outcomes. METHODS A total of 80 fetuses prenatally diagnosed with atrial isomerism were retrospectively analyzed between 1999 and 2011 at a single institution. RESULTS Of 43 fetuses with prenatally diagnosed right atrial isomerism (RAI), 40 cases were analyzed. The diagnostic accuracy was 93%. Th...

Journal: :British heart journal 1982
J C Huhta J F Smallhorn F J Macartney

At present there is no reliable method of recognising atrial isomerism by two dimensional echocardiography. We therefore used two dimensional echocardiography to examine 158 patients including 25 with atrial isomerism and four with situs inversus. Particular attention was paid to the short and long axis subcostal scans of the abdomen. Using the position of the inferior vena cava and the aorta w...

2017
Jerry A. Boatz Mark S. Gordon

Bond-stretch isomerism is predicted not to occur in the parent compound Si4H6 and the substituted 1,3-di-tert-butyl derivative, although the existence of bond-stretch isomerism in the 1,3-dimethyl derivative is a possibility. Bulky bridgehead moieties induce a preference for a short Si−Si bridge bond, while a longer bridge bond length (2.840 Å at the MP2/6-31G(d,p) level) is predicted for the u...

1999
F. R. Xu P. M. Walker R. Wyss

Two-quasiparticle K58 isomeric states in the A;130 and 180 regions are studied with configurationconstrained calculations of potential-energy surfaces. Strong shape-polarization effects due to the two quasiparticles are found. In particular, the nuclei Pb,Hg, and Te can be polarized from ground-state spherical or oblate shapes to prolate shapes, indicating a combination of K isomerism and shape...

Journal: :The Journal of Thoracic and Cardiovascular Surgery 1989

2015
James O Thomas Hugo D Andrade Benjamin M Mills Neil A Fox Heinrich J K Hoerber Charl F J Faul

The self-assembly of two emeraldine base tetra(aniline) derivatives is investigated using scanning tunneling microscopy. A combination of the scanning tunneling microscopy data and calculations reveals the presence of predicted cis/trans isomerism in this oxidation state. This isomerism is shown to hinder self-assembly into ordered structures, and provides indications as to why the properties o...

2005
Jack DeRuiter

The ester functionality does not introduce a center of asymmetry and thus optical and geometric isomerism does not result from the presence of this functional group. The ester functionality (the carbonyl and ether oxygen) is composed of an sp hybridized carbon so it cannot be chiral, and since there is free rotation about the ether bond geometric isomerism also is not possible at the sp center....

Journal: :British heart journal 1995
M H Wu J L Lin J K Wang I S Chiu M L Young

There are reports that in right atrial isomerism the conduction system has paired sinus nodes and paired atrioventricular nodes. Electrophysiological studies were performed in two patients with right atrial isomerism. One patient had a delta wave on the surface electrocardiogram without tachycardia attacks. The other, who did not have manifest pre-excitation, had recurrent narrow QRS tachycardi...

Journal: :Proceedings of the National Academy of Sciences of the United States of America 2007
Dariush Ajami Julius Rebek

Reversible encapsulation complexes create spaces where two or more molecules can be temporarily isolated. When the mobility of encapsulated molecules is restricted, different arrangements in space are possible, and new forms of isomerism ("social isomerism") are created: the orientation of one encapsulated molecule influences that of the other in the confined space. Expansion of a capsule's len...

2002
Alessandro Giamberti John E. Deanfield Robert H. Anderson Marc R. de Leval

Objective: Totally anomalous pulmonary venous connection directly to the superior caval vein is unusual. It is frequently associated with major congenital heart defects such as the syndrome of right isomerism. While improved results have been reported recently for the isolated form, complex cases are still associated with a higher mortality. Methods: We undertook surgical correction in nine pat...

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