Modification of Styrene-maleic anhydride copolymer, synthesized in toluene using benzoyl peroxide (BPO) as initiator, through graft copolymerization of hydrophilic monomer, acrylic acid, (AAc), has been carried out in aqueous medium by chemical and gamma radiation methods. Optimum conditions pertaining to maximum percentage of grafting were evaluated as a function of different reaction paramete...

The extraction of cellulose from sisal fiber was done initially using the steam explosion method. Extracted cellulose was grafted with acrylic acid in the presence of ceric ammonium nitrate redox initiator. The grafting phenomenon taking place between cellulose and the acrylic acid was proved by Fourier transform infrared spectroscopy (FTIR). The prepared graft copolymer was used as adsorbent f...

Micron thick, well-organized mesoporous TiO(2) films with high porosity and good connectivity were synthesized by templating an amphiphilic graft copolymer for solid-state dye-sensitized solar cells.

A basic investigation on the removal of Cu(II) and Ni(II) ions from metal solution by crosslinked chitosan-g-acrylonitrile copolymer was conducted in a batch adsorption system. Graft copolymers of crosslinked chitosan (CLCS) with acrylonitrile (AN) were prepared by free radical polymerization using initiator ceric ammonium nitrate as redox system. Graft copolymerization was confirmed by FTIR, X...

Poly(aminobenzene sulfonic acid) (PABS) and polyethylene glycol (PEG) were covalently attached to single-walled carbon nanotubes (SWNTs) to form water-soluble graft copolymers. Quantitative near-IR (NIR) spectroscopic studies of these SWNT graft copolymers indicate a water solubility of about 5 mg/mL, and atomic force microscopy studies show a fairly uniform length and diameter. On the basis of...

Syntheses of wholly natural polymeric linseed oil (PLO) containing peroxide groups have been reported. Peroxidation, epoxidation and/or perepoxidation reactions of linseed oil, either under air or under oxygen flow at room temperature, resulted in polymeric peroxides, PLO-air and PLO-ofl, containing 1.3 and 3.5 wt.-% of peroxide, with molecular weights of 2 100 and 3 780 Da, respectively. PLO-a...

A new potassium persulfate redox system has been investigated for the graft polymerization of vinyl monomers. In this study potassium persulfate system was used for initiation the polymerization. Graft polymerization of acrylonitrile (AN) onto starch (Sta) was carried out in aqueous solution using potassium persulfate (I) redox system. It was found that the percentage of grafting and rate of gr...