نتایج جستجو برای: hartwig reaction
تعداد نتایج: 412714 فیلتر نتایج به سال:
The Buchwald–Hartwig amination of arylhalides with the Pd–Josiphos complex is a very useful process for generation primary amines using ammonia as reactant. Density-functional theory (DFT) calculations are carried out to examine reaction mechanism this process. Although general C–N cross-coupling known, there still some open questions regarding effect chelate phosphine ligand and role base in R...
The direct arylation of N-(2-pyridyl) substituted anilines is described. Arylation takes place in ortho position to the amine functionality and is directed by the pyridine N-substituent. Remarkably, N-arylation was never observed as a competing process even though conditions also suitable for Buchwald-Hartwig reactions were applied. The scope of the reaction was investigated in terms of aryl do...
We report a procedure to linearly scale-up the synthesis of 2,8-bis(3,6-di-tert-butyl-9H-carbazol-9-yl)dibenzothiophene-S,S-dioxide (compound 4) and 2,8-bis(10H-phenothiazin-10-yl)dibenzothiophene-S,S-dioxide (compound 5) using Buchwald-Hartwig cross-coupling reaction conditions. In addition, we demonstrate a scaled-up synthesis of all non-commercially available starting materials that are requ...
CONTEXT A high number of hospitalized children do not receive adequate sedation due to inadequate evaluation and use of such agents. With the increase in knowledge of sedation and analgesia in recent years, concern has also risen, such that it is now not acceptable that incorrect evaluations of the state of children's pain and anxiety are made. OBJECTIVE A comparison between the Comfort and H...
Cyclic hexamers consisting of a 4-octyl, 4-octyloxy and 4-(2-ethylhexyloxy)triphenylamine unit were synthesized via Buchwald-Hartwig cross coupling reaction using A-A, B-B type monomers in order to avoid the formation other cyclic oligomers such as pentamer heptamer. Unlike different size oligomers, all we examined showed clear cold crystallization 165-240°C DSC thermograms. Resulting character...
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