Understanding the interaction between a fluid and a solid phase is of fundamental importance to the design of an adsorption process. Because the heat effects associated with adsorption are comparatively large, the assumption of isothermal behavior is a valid approximation only when uptake rates are relatively slow. In this article, we propose to determine when it is needed to choose the isother...

Statherin is a salivary protein that inhibits the nucleation and growth of hydroxyapatite crystals in the supersaturated environment of the oral cavity. The thermodynamics of adsorption of statherin onto hydroxyapatite crystals have been characterized here by isothermal titration calorimetry and equilibrium adsorption isotherm analysis. At 25 degrees C, statherin adsorption is characterized by ...

The aim of this investigation was to study the relationship between activation factors and adsorption of cationic dye, methylene blue MB, by activated bentonite. The adsorption index was investigated as a function of acid type, time and temperature. A commercial bentonite was selected as a starting material and the effect of heat treatment on MB adsorption were determined in a batch setup. Thou...

Title of Document: REVIEW OF THERMAL ENERGY STORAGE TECHNOLOGIES AND EXPERIMENTAL INVESTIGATION OF ADSORPTION THERMAL ENERGY STORAGE FOR RESIDENTIAL APPLICATION Gang Li, Master of Science, 2013 Directed by: Research Professor Yunho Hwang, Ph.D. Mechanical Engineering Thermal energy storage (TES) technologies can reduce or eliminate the peak electric power loads in buildings, and utilize benefit...

The efficient use of the limited resources on earth is a critical factor to sustainable life. The development of better catalysts can make a significant contribution. Complete understanding of the catalytic activity would facilitate the design and control of specific catalytic processes. Consequently, by tuning of the catalytic reactivity, the amount of energy to run a reaction and the amount o...

Recently interest in adsorption cooling systems has increased due to their capability to utilise low grade heat sources and environmentally friendly refrigerants. Currently, most of the commercially available adsorption cooling systems utilise granular packed adsorbent beds. Enhancing the heat transfer process inside the adsorbent bed will improve the overall efficiency of the adsorption system...

A one-dimensional soil model has been developed to better predict heat and water exchanges in arid and semiarid regions. New schemes to calculate evaporation and adsorption in the soil were incorporated in the model. High performance of the model was confirmed by comparison of predicted surface fluxes, soil temperature, and volumetric soil water content with those measured in the Negev Desert, ...

adsorbed natural gas has various advantages and is relatively more economical than liquefaction and compression. carbon nanotubes can be introduced as a new candidate for natural gas storage. in this study, adsorption of methane was firstly studied on the as-prepared multi-walled carbon nanotubes, and then chemical and physical treatment of mwcnts was performed to enhance the methane adsorption...

The surface heterogeneity of multiwalled carbon nanotubes (MWCNTs) is studied on the basis of adsorption isotherms from dilute aqueous phenol and dopamine solutions at various pH values. The generalized Langmuir-Freundlich (GLF) isotherm equation was applied to investigate the cooperative effect of the surface heterogeneity and the lateral interactions between the adsorbates. The theoretical is...

A differentially pumped, capillary array molecular beam source is used to study the reversible adsorption of CO on CO/Pd~111! @Q(CO)50.55# and vinylidene/Pd~111! @Q(vinylidene)51.0# at 300 K. Differentially pumping allows the beam to equilibrate rapidly ~in ;2 s! while maintaining good beam uniformity. The isosteric heat of adsorption of reversibly held CO on a surface precovered with 0.55 mono...