نتایج جستجو برای: hyperbranched polymer
تعداد نتایج: 93884 فیلتر نتایج به سال:
Fully atomistic molecular dynamics simulations were employed in order to examine in detail the self-assembly characteristics and the complexation behavior of the anticancer drug doxorubicin with PEGylated hyperbranched polyesters in an aqueous environment. We have examined two variants of the polymeric compound by altering the length of the hydrophilic poly(ethylene glycol) arms attached to the...
We study theoretically the scattering imprint of a number of branched supramacromolecular architectures, namely, polydisperse stars and dendrimeric, hyperbranched structures. We show that polydispersity and nature of branching highly influence the intermediate wave vector region of the scattering structure factor, thus providing insight into the morphology of different aggregates formed in poly...
A cobalt-containing hyperbranched polydiyne shows refractive indexes (n) as high as 1.713-1.813 in the long wavelength region, which can be tuned to a large extent (Deltan up to approximately 0.048) by UV irradiation; the polymer can also function as a spin-coatable catalyst for the growth of carbon nanotubes.
We have developed and studied a novel high-strength glass-ionomer cement system composed of poly(acrylic acid) with different molecular architectures. These poly(acrylic acid) polymers were synthesized via ATRP technique. The effects of arm number and branching on reaction kinetics, viscosity, and mechanical strengths of the formed polymers and cements were evaluated. The results showed that un...
We report results from Brownian dynamics computer simulations of systems comprised by two terminally charged hyperbranched molecules preferentially branched in the periphery, with an oppositely charged linear chain of varying length. Comparison of the findings from the present study to stoichiometric counterparts and to analogous dendrimer-based complexes, reveal that the presence of the second...
s of Papers A-49 Department of Chemistry for Materials
Porous hyperbranched conjugated polymer nanoparticles with an average particle size of 20-60 nm and a specific surface area of 225 m(2) g(-1) have been prepared through Suzuki polymerization in a miniemulsion, which could be stably dispersed in common organic solvents after complete removal of surfactants. Furthermore, a simple spin-coating method for the preparation of homogeneous transparent ...
A novel well-defined linear poly(ε-caprolactone) (P1) containing terminal azobenzene and ethyne groups was successfully synthesized through tin-catalyzed ring-opening polymerization of ε-caprolactone in the presence of N,N′-bis(2-hydroxyethyl)-4-(3ethynylphenylazo)aniline (BHA) in bulk. Subsequent reactions allowed the synthesis of the corresponding bromoester end-functionalized polymer (P2), w...
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