In the asymmetric unit of the title compound {systematic name: N'-(2,4-di-methyl-phen-yl)-N-[N-(2,4-di-methyl-phen-yl)carbox-imido-yl]-N-methyl-methanimidamide}, C19H23N3, which is a formamidine pesticide, there are two independent and conformationally similar mol-ecules, with the dihedral angle between the mean planes of the 2,4-di-methylbenzene rings in each mol-ecule being 41.63 (6) and 42.0...

3-Aryl-amido/imido-methyl-4-hydroxy-phenyl-acetophenones (I) were prepared in excellent yields by condensing equilmolar amounts or p-hydroxy acetophenones and aryl-amido/imido-alcohols in the presence of conc. H2SO4. Reaction of (I) with semicarbazide, hydro-chloride in ethanol afforded 3-Aryl-amido/imido-methyl-4-hydroxyphenyl-acetophenone-semicarbazones (II) in the yields ranging from 60-70%....

Four novel dimeric bis-μ-imido bridged metal-metal bonded oxidomolybdenum(V) complexes [MoV2O2L'21-4] (1-4) (where L'1-4 are rearranged ligands formed in situ from H2L1-4) and a new mononuclear dioxidomolybdenum(VI) complex [MoVIO2L5] (5) synthesized from salen type N2O2 ligands are reported. This rare series of imido-bridged complexes (1-4) have been furnished from rearranged H3L'1-4 ligands, ...

We report the uranium(VI) carbene imido oxo complex [U(BIPM(TMS))(NMes)(O)(DMAP)2] (5, BIPM(TMS) = C(PPh2 NSiMe3)2; Mes = 2,4,6-Me3C6H2; DMAP = 4-(dimethylamino)pyridine) which exhibits the unprecedented arrangement of three formal multiply bonded ligands to one metal center where the coordinated heteroatoms derive from different element groups. This complex was prepared by incorporation of car...

Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN(2)(N-N) unit.

Phosphinoamide ligands have been utilized to link a Co(I) center to a Nb or Ta imido fragment. The resulting heterobimetallic complexes, ICo(Ph(2)PN(i)Pr)(3)M=N(t)Bu, have weakened dative metal-metal interactions as a result of the strongly donating imido ligand. These complexes can be reduced by 2 electrons to generate dinitrogen-bound complexes.

The first rare earth metal terminal imido complex has been isolated and structurally characterized. The complex has an extremely short M-N bond length and a nearly linear M-N-C angle. DFT studies showed two p orbitals of N(imido) atom form two bonds with two d orbitals of rare earth metal ion.

21 vanadium bis-phenolate benzimidazolyidene complexes spanning three oxidation states have been investigated. Special emphasis is thereby laid on their salt metathesis reactivity and the accessibility of +IV state by reductive or oxidative routes, starting from vanadium(V) vanadium(III) respectively. While route highly depended reducing agent material used, gives clean access to vanadium(IV) d...

The effects of various substrates and alternative substrates on the hydrolytic activity of beef heart mitochondrial ATPase was examined. It was found that ATP and ADP are competitive inhibitors of ITP hydrolysis, and that in the presence of either ATP or ADP, ITP hydrolysis showed positive cooperativity. IDP inhibited ITP hydrolysis and caused positive cooperativity. When ITP was present during...