Syncope precipitated by sneezing in an adult male associated with an Arnold-Chiari type I malformation and basilar invagination presents a clinical problem in the differential diagnosis and pathological anatomy of Valsalva-related syncope. An abnormally acute clivoaxial angle, small foramen magnum, and type I Arnold-Chiari malformation appear to be a combination of features intolerant of Valsa...

Density functional theory is applied to ion-induced nucleation of polarizable multipolar molecules. The asymmetric nature of the ion–molecule interaction is shown to cause the sign preference in ion-induced nucleation. When the ion–molecule interaction is weak, the observed sign preference is consistent with that of the bare ion–molecule interaction potential and decreases with increasing super...

My NMR career started in 1980 when I joined the Division of Molecular Pharmacology at the Medical Research Council’s National Institute of Medical Research (NIMR) located in Mill Hill, London. I had been recruited 18 months previously by the director of NIMR, Sir Arnold Burgen, while still a medical student at University College Hospital Medical School, on the basis of the work I had published ...

We have reported the use of carboxylate-alumoxanes as efficient nucleating agents for isotactic polypropylene (iPP) with a possible structural correlation to the nucleation efficiency. The unique, butterfly-like structure of carboxylate-alumoxanes correlates well with the nucleation characteristics of iPP and, for the first time, the impact of a thermally induced, crystalline transition of carb...

Molecular dynamics simulations were performed for CO2 dissolved in water near silica surfaces to investigate how the hydrophilicity and crystallinity of solid surfaces modulate the local structure of adjacent molecules and the nucleation of CO2 hydrates. Our simulations reveal that the hydrophilicity of solid surfaces can change the local structure of water molecules and gas distribution near l...

Abstract The complex and incompletely understood phenomenon of shear-induced crystallization polymers may be nowadays analysed via the in situ POM-shear stage methodology. In this research, two main issues were investigated with use Linkam CCS450 shear connected POM microscope. It was found that secondary nucleation tree well-known temperature regimes plays greater role overall kinetics than in...

PURPOSE Gokhsuradi churna is an ayurvedic formulation, was investigate for antiurolithiatic activity. METHODS Calcium oxalate crystallization was induced by the addition of 0.01M sodium oxalate solutions in synthetic urine and nucleation method. RESULTS The effect of Gokhsuradi Churna exhibited a concentration dependent inhibition of on calcium oxalate crystallization and nucleation. CONC...