a nanocomposite membrane cu2+ ion-selective electrode has been constructed using a new compound ethyl 1,2,3,4-tetrahydro-4-(4-methoxyphenyl)-6-methyl-2-oxopyrimidine-5-carboxylat (etmoc) as a neutral ionophore. the electrode works properly. it responds to cu2+ ion with a sensitivity of 29.5 ± 0.2 mv/decade over the range 1.0 × 10−9 to 5.0 × 10−1m at ph 3.0-8.0. the limit of detection was 4.5 × ...

fluoride is recognized as an effective agent for dental caries prevention. generally, the main source of fluoride intake is drinking water. in this study, fluoride content in 18 commercial brands of bottled waters was investigated. six samples from each batch of 18 iranian commercial brands of bottled waters were supplied. the fluoride content of samples was analyzed by fluoride ion selective e...

2-amino-n-benzthioazolyl benzamide (abtb) was synthesized, characterized and used for thefabrication of a potentiometric sensor for cu2+ metal ions. the electrode exhibits linear response to cu(ii) over a wide concentration range (4.79×10 -8 – 1.85×10 -1 m) with nernstian slope of 30 ± 1.5 mvper decade. the electrode can be used in the ph range from 2 to 9. it has a fast response time of about1...

In this work we introduce a practical use of synthesized Schiff base metal complex in sensing application. A new perchlorate-selective electrode based on the complex N, N'-4-nitro-phenylmethanebis-(salicylaldiminato) copper (II) [CuL] as the membrane carrier was developed. The electrode exhibits a good  Nernstian slope of -55.0 ± 1.0 mV/decade and a linear range of  for perchlorate. The lim...

a new poly(vinylchloride) membrane sensor for cr3+ ions based on di (benzylamino)glyoxime asan ionophore was prepared. the electrode has a linear dynamic range 1×10-6-1×10-1 mol l-1,with anernstian slope of 20.3 ± 0.5 mv per decade and a detection limit of 2×10-7. it has a fast responsetime of

In this work a new chemically modified carbon paste electrode was constructed for accurate, simple, sensitive and selective determination of molybdenum (VI) ions. The results of modified electrode by an ion imprinted polymer were compared with those obtained with carbon paste electrode. The results showed the stripping peak currents had a dramatic increase at the modified electrode. Under the o...

A PVC membrane Cr(III) ion selective electrode has been constructed using 2H-1,4-benzothioazine-2,3(4H)dione dioxime (BTD) as membrane carrier. The influence of membrane composition on the electroderesponse was studied. The electrode exhibits a Nernstian response over a Cr(III) concentration range of 1.0 x10 6 to 1.0>< 10-1 M (r = 0.99) with a slope of 19.5 ± 0.5 mV per decade of concentration,...

N-(2H-[1,2,4]thiadiazolo[2,3-a]pyridine-2-ylidene)benzamide was used as a selective sensing material in the PVC membrane to construction of a new chromium ion selective electrode. This liquid membrane electrode worked well with a Nernstian response of 19.7 ±0.4 mV decade-1 of Cr(III) in a wide dynamic concentration range of 8.0× 10-6-1.0×10-1 M. The electrode had relatively short response time ...