amide-iminol tautomerism was studied for ionized oxamic acid (oa+•) in the gas phase using thedft method with the ub3lyp functional and various basis sets {6-31++g(d,p), 6-311+g(d,p), and augcc-pvdz}. among twenty tautomers-rotamers possible for oa+•, eleven isomers were found to bethermodynamically stable. similarly as for the neutral molecule, ionization (oa → oa+• + e) favors theamidization ...

Ionization suppression can be defined as the decrease of photoinduced atomic ionization rates with an increased applied field intensity. The temporal and spatial intensity distribution of a focused laser pulse introduces difficulty in observing ionization suppression. An analysis of the effect of a temporally Gaussian laser pulse on ionization suppression from Rydberg levels is given. It is fou...

Ambient ionization is a set of mass spectrometric ionization techniques performed under ambient conditions that allows the direct analysis of sample surfaces with little or no sample pretreatment. Using combinations of different types of sample introduction systems and ionization methods, several novel techniques have been developed over the last few years with many applications (e.g., food saf...

A direct solution of the time-dependent Schrödinger equation ~TDSE! for a two-electron model atom in a strong electromagnetic field is used to extract probabilities for both single and double electron ionization. For three-photon ionization at a moderately strong intensity, the TDSE calculations find single ionization at 62%, single ionization with excitation at 10%, and double ionization at 3%...

Abstract We calculate the cross-section of ionization by free-electron impacts in high or moderate density plasmas. show that so-called potential depression (IPD) strongly affects magnitude high-density domain. use well-known IPD formulas Stewart–Pyatt and Ecker–Kröll. A more recent approach based on classical molecular dynamics simulation is also investigated. The latter provides an alternativ...

Theory and experiment are compared for the electron-impact double ionization of Mg. Direct ionization cross sections, involving the simultaneous ionization of both 3s electrons, are calculated using a non-perturbative time-dependent close-coupling method. Indirect ionization cross sections, involving the ionization of either a 2p or 2s electron followed by autoionization, are calculated using a...

Time-dependent close-coupling and time-independent distorted-wave methods are used to calculate the electron-impact double-ionization cross section for the 1s22s2 ground configuration of the B+ atomic ion. The direct double-ionization cross section is calculated using the non-perturbative close-coupling method between the direct double-ionization threshold of 63.1 eV and the 1s ionization thres...