Layer-by-layer (LbL) films containing cationic polyelectrolytes and anionic bioactive molecules such as DNA are promising biomaterials for controlled and localized gene delivery for a number of biomedical applications including cancer DNA vaccine delivery. Bioreducible LbL films made of disulfide-containing poly(amido amine)s (PAAs) and plasmid DNA can be degraded by redox-active membrane prote...

Hybrid organic/inorganic perovskite solar cells have been rapidly evolving with spectacular successes in both nanostructured and thin-film versions. Herein, we report the use of a simple sol-gel-processed NiO nanocrystal (NC) layer as the hole-transport layer in an inverted perovskite solar cell. The thin NiO NC film with a faceted and corrugated surface enabled the formation of a continuous an...

A photoluminescent multilayer film based on Keggin-type polyoxometalate PMo12O40 3 (PMo12) and transition metal complex tris(2,2-bipyridine) ruthenium [Ru(bpy)3] 2+ (Ru(bpy)) was prepared by using layer-by-layer assembly(LBL). The formation of multilayer film was monitored by ultraviolet absorption spectra. The absorption intensity of characteristic peaks increase with a four-layer cycle, indic...

Subject to a compressive membrane force, a solid film on a liquid layer may form wrinkles. When the solid film is very thin, surface stresses contribute to the membrane force. When the liquid layer is very thin, the two interfaces bounding the liquid interact with each other through forces of various physical origins. We formulate the free energy of the solid-on-liquid structure, and carry out ...

abstractbackgrounds: md-55-2 is one of the radiochromic film models with the sensitivity suitable for dose measurements ranging from 5 to 100 gy.  however, this lower limit makes the film impractical for its applications in many areas such as brachytherapy source dosimetry.materials and methods: in this project, the useful range of the film has been extended by using a multilayer film technique...

Using neutron reflectivity, we found that there is no intrinsic depletion layer at a deuterated polystyrene (dPS) film and deuterium oxide (D(2)O) interface. A spun-cast film is susceptible to contamination on its surface from its surroundings during sample preparation. A contamination layer of hydrogenated organic material will be detected as a reduced scattering length density layer at the in...

In this research work, silica nano-porous thin films were deposited on glass substrates by layer by layer method. The thin films were calcinated at various calcination temperatures (200, 300, 400, and 500 °C). The morphology, surface characteristics, surface roughness and hydrophilic properties of the thin films were investigated by field emission scanning electron microscopy, attenuated total ...

We report thickness-dependent morphologies of a Pd film on n-layer graphenes. Via Raman spectroscopy-based technique, obvious charge transfer has been observed among Pd and graphenes, which is also dependent on the layer number. With the increase of the layer number, the Pd film becomes coarser, and the electron transfer becomes lower.

A theory is presented for the dispersion relations of the nonlinear phonon-polaritons arising when phonons are coupled to the electromagnetic waves in multilayered structures of nonlinear materials. The calculations are applied to a multilayered structure consisting of a thin film surrounded by semi-infinite bounding media where each layer may have a frequency dependent dielectric function and ...

In this work, we present an experimental technique for obtaining highly ordered L1 FePt-oxide thin film media at moderate deposition temperatures. In most previous studies, a FePt-Oxide layer is directly deposited on a (001) textured MgO layer. By introducing a buffer layer in between the FePt-oxide layer and the MgO underlayer, we are able to substantially enhance the L1 ordering of the FePt-o...