Natural nacre, which consists of almost 95 vol% inorganic content (calcium carbonate) and 5 vol% elastic biopolymers, possesses a unique combination of remarkable strength and toughness, which is attributed to its hierarchical nano-/ microscale structure and precise inorganic–organic interface. Inspired by the intrinsic relationship between the structures and the mechanical properties lying in ...

Annealing of C60 in hydrogen at temperatures above the stability limit of C-H bonds in C60H x (500-550 °C) is found to result in direct collapse of the cage structure, evaporation of light hydrocarbons, and formation of solid mixture composed of larger hydrocarbons and few-layered graphene sheets. Only a minor part of this mixture is soluble; this was analyzed using matrix-assisted laser desorp...

In this study, the free vibration behavior of orthotropic rectangular graphene sheet embedded in an elastic medium under biaxial pre-load is studied. Using the nonlocal elasticity theory, the governing equation is derived for single-layered graphene sheets (SLGS). Differential quadrature method (DQM) has been used to solve the governing equations for various boundary conditions. To verify the a...

Introduction Graphene oxide is the liquid oxidation of graphite powder, and consists of a single atomic carbon network derivitized by phenol hydroxyl and epoxide groups on the basal plane and carboxylic acid groups at the edges[1, 2]. The chemical functionalization breaks the extended π−π conjugation of graphene, resulting in an insulating material. However the conductivity may be partially res...

In this paper, an atomistic based finite element model is developed to investigate the influence of topological defects on mechanical properties of graphene. The general in-plane stiffness matrix of the hexagonal network structure of graphene is found. Effective elastic modulus of a carbon ring is determined from the equivalence of molecular potential energy related to stretch and angular defor...

A recently discovered two-dimensional (2D) layered material phosphorene has attracted considerable interest as a promising p-type semiconducting material. In this work, thermal conductivity (κ) of monolayer phosphorene is calculated using large-scale classical non-equilibrium molecular dynamics (NEMD) simulations. The predicted thermal conductivities for infinite length armchair and zigzag phos...

Two dimensional atomic sheets, such as graphene and transition metal dichalcogenides (TMDs), have been widely studied as electronic materials for flexible nanoelectronics applications due to the high flexibility enabled by their natural 2D layered crystal structure. However, with the growing need for both high speed and low power consumption in realistic applications, TMDs with relatively low m...

We present a fabrication method producing large and flat graphene flakes that have a few layers down to a single layer based on substrate bonding of a thick sample of highly oriented pyrolytic graphite (HOPG), followed by its controlled exfoliation down to the few to single graphene atomic layers. As the graphite underlayer is intimately bonded to the substrate during the exfoliation process, t...

We propose a new family of layered sp(2)-like carbon crystals, incorporating five-, six-, and seven-membered rings in 2D Bravais lattices. These periodic sheets can be rolled so as to generate nanotubes of different diameter and chirality. We demonstrate that these sheets and tubes are metastable and more favorable than C60, and it is also shown that their mechanical properties are similar to t...