Adsorption of lead(II) as a major heavy metal pollutant onto nano-adsorbents of Andalusite, Kyanite and Sillimanite was studied in a batch system. Nano­-adsorbents were prepared via crushing, using a planetary ball mill and then characterized by different analyses such as: SEM, XRD, XRF and FT-IR. Major factors affecting the adsorption process were studied including pH, adsorbents dosage, initi...

This study examines the adsorption isotherms, kinetics and mechanisms of Pb²(+) sorption onto waste cow bone powder (WCBP) surfaces. The concentrations of Pb²(+) in the study range from 10 to 90 mg/L. Although the sorption data follow the Langmuir and Freundlich isotherm, a detailed examination reveals that surface sorption or complexation and co-precipitation are the most important mechanisms,...

The adsorption performance and mechanism of extracellular polymeric substances (EPS) extracted from Klebsiella sp. J1 for soluble Pb (II) were investigated. The maximum biosorption capacity of EPS for Pb (II) was found to be 99.5 mg g(-1) at pH 6.0 and EPS concentration of 0.2 g/L. The data for adsorption process satisfactorily fitted to both Langmuir isotherm and pseudo-second order kinetic mo...

The identity of the predominating lead(ii) species in hyper-alkaline aqueous solution has been determined by Raman spectroscopy, and ab initio quantum chemical calculations and its structure has been determined by EXAFS. The observed and calculated Raman spectra for the [Pb(OH)3](-) complex are in agreement while they are different for two-coordinated complexes and complexes containing Pb[doubl...

An uptake of zinc (Zn), copper (Cu), and lead (Pb) from aqueous solutions by ion exchange on natural zeolitic tuff has been studied. The Croatian zeolite clinoptilolite from the Donje Jesenje deposit has been used as a natural ion exchanger. The efficiency of removal is higher for Pb and Cu than for Zn ions. Measured concentrations of Si in the liquid phase identify the detachment of the alumin...

OBJECTIVE To study the characterization apportionment of main ion concentrations of PM10 under the influence of trajectory wind direction in London. METHODS PM10 samples from 1 May 1995 to 30 October 1995 of Oxford Street of Central London were collected, the metals and anions of which were measured using atomic absorption spectrometry (AAS) and ion chromatography (IC). Composite trajectories...

We present a new multielement masking method using magnesium hydroxide coprecipitation for the selective determination of Pb by differential pulse anodic stripping voltammetry (DPASV). The recovery of Pb in the masking method was over 95%, while interfering ions (Cd(2+), Co(2+), Cu(2+), Fe(3+), Mn(2+), and Ni(2+)) could be removed at 100% from the analytical sample. A linear regression was obta...

The purpose of this study is to analyze the chemical composition of wet precipitation in samples collected at three stations in the Candiota region in the Brazilian state of Rio Grande do Sul (RS). Samples were collected in 2004. Variables analyzed in wet precipitation were pH, conductivity, and concentration of Cl-, NO3-, SO4(2-) F-, Na+, Ca2+, Mg2+, K+, NH4+, Cu, Zn, Fe, Mn, Pb, Ni, Cd, Co, a...

Background: To determine whether local complications at the site of pacemaker implantation indicate infection of the intravascular part of the lead as well as of the pacemaker pocket. Methods: 105 patients admitted for local inflammatory findings, impending pacemaker or lead exteriorisation, frank pacemaker or lead exteriorisation, or overt infection were studied prospectively. After systematic...