A new method was established for the simultaneous determination of the migration amounts of bisphenol A (BPA) and phenol from polycarbonate (PC) bottles based on subcritical water extraction (SWE) and high performance liquid chromatography. The optimum extraction conditions included an extraction temperature of 120 degree C, a pressure of 6.89 MPa (1000 psi), a static extraction time of 1 h and...

A new, rapid and sensitive microextraction technique named vortex-assisted liquid-liquid-liquid microextraction (VALLLME) is proposed. The complete extraction process involves two steps. First, a vortex-assisted liquid-liquid microextraction (VALLME) procedure was used to extract the analytes from a relatively large volume of sample (donor phase) to a small volume of organic solvent (intermedia...

Abstract In this study, microfunnel-supported liquid-phase microextraction method (MF-LPME) was optimized and applied for the determination of some chlorophenoxyacetic acids (CPAAs) from natural water samples. The extraction was performed with 540 μL toluene which was retained at the surface of the sample solution using an upside down microfunnel. After the extraction, toluene was moved in...

In the paper, in order to pre-concentrate and measure the low values of Cu ions, the new, simple,quick and very sensitive method of Dispersed Liquid-Liquid Micro Extraction (DLLME) coupledwith flame Atomic Absorption spectrometry (AA) has been utilized. The DLLME techniquecoupled with AA )AA-DLLME) was run inside one narrow tube which constitute aqueous samples.In this m...

Imazalil ([1-(β-allyloxy-2,4-dichlorophenethyl)imidazole]) is a systemic chiral fungicide used in postharvest protection of citruses against fungi development for during storage and transportation. The chemical structure of imazalil shows an asymmetric carbon in the C7 position. These enantiomers may have different toxicity. A method for both chiral enantiomers extraction and determination in o...

gallium extraction from jajarm bayer process liquor (jajarm, iran) was investigated using microemulsions. also the behavior of aluminum was studied as an impurity. kelex100 (4-ethyl, 1-methyl, 7-octyl, 8-hydroxyquinoleine), iso-decanol and n-butanol, and kerosene were used as the surfactant, co-surfactant, and oil phase, respectively. ternary phase diagrams were produced using various co-surfac...

atechnical feasibility study has been conducted on production of nano- and micro-fibrils from nylon 6/polypropylene grafted with maleic anhydride/polypropylene blended films. fibrils are prepared in four consecutive steps.in the first step the polymers melt blended in an extruder with and without compatibilizers to produce chips; in the second step films are extruded from polymer blends chips, ...

The advantage of the application of the supercritical extraction in contrast to the conventional methods to prepare micro and nanoparticles is that the product no longer is exposed to high temperatures for a long time. Furthermore, the supercritical extraction offers the possibility to reduce the content of the residual organic solvent in the final product because of the high solubility of orga...