Here we demonstrate that the anomalous magnetic properties of iron oxide nanoparticles are correlated with defects in their interior. We studied the evolution of microstructure and magnetic properties of biphasic core|shell Fe(1-x)O|Fe(3-δ)O4 nanoparticles synthesized by thermal decomposition during their topotaxial oxidation to single-phase nanoparticles. Geometric phase analysis of high-resol...

Present work describes the formation of α-Fe2O3@SiO2 core shell structure by systematic layer by layer deposition of silica shell on core iron oxide nanoparticles prepared via various solvents. Sol-gel method has been used to synthesize magnetic core and the dielectric shell. The average crystallite size of iron oxide nanoparticles was calculated ∼20 nm by X-ray diffraction pattern. Morphologic...

In this study, multifunctional hybrid nanoparticles composed of iron platinum (FePt), silica (SiO2), and gold nanoparticles (AuNPs) had been developed for surface-enhanced Raman scattering (SERS) application. Core-shell structure of SiO2 and FePt nanoparticles (FePt@SiO2) was fabricated through sol-gel process and then immobilized gold nanoparticles onto the surface of FePt@SiO2, which displays...

Polycrystalline iron phosphide coated iron oxide and hollow iron phosphide nanoparticles were synthesized by sonichemistry. Structure analysis indicated that the diameters of these nanoparticles were less than 14 nm, and the core–shell and hollow nanoparticles are Fe3O4–FeP and FeP, respectively. Magnetic measurement demonstrated that both the core–shell Fe3O4–FeP and hollow FeP nanoparticles e...

Chitosan functionalized Fe3O4-Au core shell nanoparticles have been prepared using a two-step wet chemical approach using NaBH4 as reducing agent for formation of Au in ethylene glycol. X-ray diffraction studies shows individual phases of Fe3O4 and Au in the as prepared samples with crystallite size of 5.9 and 11.4 nm respectively. The functionalization of the core-shell nanostructure with Chit...

Core-shell nanoparticles have attracted surging interests due to their flexibly tunable resonances and various applications in medical diagnostics, biosensing, nanolasers, and many other fields. The core-shell nanoparticles can support simultaneously both electric and magnetic resonances, and when the resonances are properly engineered, entirely new properties can be achieved. Here we study cor...

Iron core gold shell nanoparticles grafted with Methotrexate (MTX) and indocyanine green (ICG) were synthesized for the first time in this study, and preliminarily evaluated for their potential in magnetic hyperthermia treatment. The core-shell Fe@Au nanoparticles were prepared via the microemulsion process and then grafted with MTX and ICG using hydrolyzed poly(styrene-alt-maleic acid) (PSMA) ...

Upconverting nanoparticles (UCNPs) are promising, new imaging probes capable of serving as multimodal contrast agents. In this study, monodisperse and ultrasmall core and core-shell UCNPs were synthesized via a thermal decomposition method. Furthermore, it was shown that the epitaxial growth of a NaGdF4 optical inert layer covering the NaGdF4:Yb,Er core effectively minimizes surface quenching d...

This study describes the surface modification of magnetic nanoparticles using two different approaches. The first approach consists of an in situ modification of the surface during the precipitation of the magnetic nanoparticles while the second approach consists of a post-modification of the surface after the formation of the magnetic nanoparticles. In the latter case, we adopted the Layer-by-...