the purpose of this study was to evaluate the exposure to mercury (hg), and to examine the various parameters, which contribute to high levels of mercury of iranian dentists in tehran. one-hundred hair samples were collected from dentists. in addition, fifty samples from a control group were taken for comparison. the survey included a structured questionnaire designed to provide information abo...

This contribution is based on our presentation at the 1 International Symposium on Sensor Science, Paris, 16-20 June 2003. It presents recent results regarding the electrochemical determination of submicromolar and nanomolar concentrations of various carcinogenic substances (nitrated polycyclic aromatic hydrocarbons, heterocyclic compounds, azo compounds, aromatic amino compounds, etc.) using b...

Minor modifications to a Coleman MAS-50A Mercury Analyser System allowed the determination of mercury by flow injection analysis. Using sample volumes of 600 mul it was possible to analyse up to 120 samples per hour, with a detection limit of 0.2 mug. l(-1) (120 pg) of mercury. The authors also report on a simple digestion procedure which replaces the time- and reagent-consuming EPA procedure, ...

In this method for quantitative determination of mercury in blood, urine, and hair, the specimen is first digested in a mixture of solid potassium permanganate and concentrated sulfuric acid. Excess oxidizing agent is reduced by hydroxylamine hydrochloride. The mercury liberated with stannous chloride is quantified by measuring its absorbance at 254 nm. This method shortens digestion time consi...

A novel chitosan-based chelating resin modified with tris(2-aminoethyl)amine moiety (CCTS-TAA) was synthesized, and its characteristics in the collection/concentration of mercury was examined. The synthesized resin showed good adsorption toward mercury in a wide pH range, and the adsorbed mercury can be easily eluted by using 2M HNO(3) without any addition of complexing agent. The resin was the...

The quantitative determination of mercury in foodstuffs is presented using a 7500i ICP-MS. Microwave digests were prepared and then analyzed by ICP-MS. To avoid memory effects often experienced with mercury, gold was added offline to all standards/samples and wash solutions to act as a cleansing agent. The instrumental setup used a second vacuum pump, the integrated sample introduction system i...

This work reports a comparative electrochemical behaviour study and p-nitrophenol analytical detection using silver solid amalgam, hanging dropping mercury, and silver electrodes. For this, square wave voltammetry was employed, where the analytical responses and the redox mechanisms could be compared for reduction processes of 4-nitrophenol by analysis of the voltammetric responses. The analyti...

A catalytic method has been developed for the determination of microgram amounts of mercury (II) based on its catalytic effect on the rate of a ligand substitution reaction. The reaction studied involved the substitution of cyanide in hexacyanoferrate (II) by resacetophenone benzoic acid hydrazone (2’, 4’dihydroxy propiophenone benzoic acid hydrazone) and the reaction was monitored spectrophoto...