In this study, we developed a simple high-throughput and cost-effective method for monitoring toxic metal ion in an environmental aqueous sample. Mercury determination with Sequential Injection Analysis system (SIAs) coupled the electrochemical detection on modified screen-printed carbon working electrode (SPCE) is alternative green analysis of mercury ion. The gold film was used as material im...

A classification of kinetics of metalloporphyrin formation is presented according to the composition of the activated complex involved in the reaction. In the reaction of large metal ions, such as mercury(II) and cadmium(II) with porphyrins, these metal ions can not fit into the porphyrin nucleus and they are out—of-plane in the metalloporphyrin. In this case the reaction is relatively fast and...

Inverse vulcanised sulfur polymer nanoparticles prepared by antisolvent precipitation–demonstrated as mercury ion absorbent in solution, showing high selectivity and capacity, membrane filters.

conclusions experimental results showed that mcns is an excellent sorbent for removal of mercury ions from petrochemical waste water. in addition, highly complex matrix of this waste does not affect the adsorption capability of mcns. results an effective hg (ii) removal (99.8%) was obtained at ph 6, with 50 mg of mcns for an initial concentration of this ion in petrochemical waste water (5.63 m...

The quenching of quantum dots' emission by some analytes (Hg(2+), Pb(2+), etc.) has long been hindering the fabrication of QD-based 'turn-on' or ratiometric fluorescent sensors for these analytes. In this study, we demonstrate a facile solution for constructing a robust FRET-based ratiometric sensor for Hg(2+) detection in water with CdTe QDs as the donor. By using the reverse microemulsion app...

A sensitive dip-and-read test strip for the determination of mercury in aqueous samples based on the inhibition of urease reaction by the ion has been developed. The strip has a circular sensing zone that containing two layers: the top layer is a cellulose acetate membrane where urease is immobilized on it; the bottom layer is a pH indicator wafer that is impregnated with urea. The principle of...

Mercury has a long history as an antimicrobial agent effective against eukaryotic and prokaryotic organisms. Despite its prolonged use, the basis for mercury toxicity in prokaryotes is not well understood. Archaea, like bacteria, are prokaryotes but they use a simplified version of the eukaryotic transcription apparatus. This study examined the mechanism of mercury toxicity to the archaeal prok...

An immunoassay that detects mercuric ions in water at concentrations of 0.5 ppb and above is described. The assay utilizes a monoclonal antibody that binds specifically to mercuric ions immobilized in wells of microtiter plates. Within the range of 0.5-10 ppb mercury, the absorbance in the enzyme-linked immunosorbent assay (ELISA) is linear to the log of the mercuric ion concentration. The quan...