نتایج جستجو برای: mesoporous silicon
تعداد نتایج: 90178 فیلتر نتایج به سال:
This work presents an innovative integration of sensing and nano-scaled fluidic actuation in the combination of pH sensitive optical dye immobilization with the electro-osmotic phenomena in polar solvents like water for flow-through pH measurements. These flow-through measurements are performed in a flow-through sensing device (FTSD) configuration that is designed and fabricated at MTU. A relat...
Silicon-based materials have widespread application as biophysical tools and biomedical devices. Here we introduce a biocompatible and degradable mesostructured form of silicon with multi-scale structural and chemical heterogeneities. The material was synthesized using mesoporous silica as a template through a chemical vapour deposition process. It has an amorphous atomic structure, an ordered ...
The purpose of this work was to study the hydrogen adsorption on the surface of mesoporous materials based on silica (SBA-16) modified with palladium via temperature. Since mesoporous silica materials have a high specific surface area, and the ordered mesoporous size of 2-10nm, they are suitable for adsorption and storage of hydrogen. SBA-16 is suitable for this purpose due to its cubic crystal...
Mesoporous templated MCM-48 silica was prepared using a C16 surfactant as template. The MCM-48 powders and thin films were characterized by different techniques. Two types of porous supports were used, namely macroporous α-alumina and silicon microsieves. The supported MCM-48 layers were applied as liquid permeable membranes in pressure-driven nanofiltration and electric field-mediated ion tran...
Silicon materials remain unused for supercapacitors due to extreme reactivity of silicon with electrolytes. However, doped silicon materials boast a low mass density, excellent conductivity, a controllably etched nanoporous structure, and combined earth abundance and technological presence appealing to diverse energy storage frameworks. Here, we demonstrate a universal route to transform porous...
Luminescent mesoporous Tb(OH)3@SiO2 core-shell nanospheres were synthesized through W/O microemulsion process at ambient temperature. The negatively charged silica favors a coating of the positively charged Tb3+ composite. Thus, silicon layer was adsorbed on the surface of Tb(OH)3 groups to form Tb-O-Si through electrostatic interaction. X-ray diffraction, field emission transmission electron m...
The co-ammonolysis of V(NMe2)4 and Si(NHMe)4 with ammonia in THF and in the presence of ammonium triflate ([NH4][CF3SO3]) leads to the formation of monolithic gels. Pyrolysing these gels produces mesoporous composite materials containing nanocrystalline VN and amorphous silicon imidonitride. Elemental mapping indicated a thorough distribution of VN with no evidence of large cluster segregation....
Significant efforts have been devoted to synthesis and characterization of engineered silicon nanostructures able to withstand the large stresses and strains produced by lithium alloying/dealloying reactions during electrochemical cycling. Less attention has been given to ensuring robust connection between silicon and its host structure in the anode. The current work develops a new methodology ...
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