The synthesis of mesoporous CuFe2O4 spinel by several nanocasting strategies (i.e., multi-step nanocasting, one step nanocasting, modified solid-liquid), in which copper and iron nitrates are used as precursors and Pluronic P123 as surfactant, is explored. We have also checked the effect of pH, citric acid and sodium citrate in multi-step nanocasting method. The modified solid-liquid method whi...

Alkyl and multifunctional organic nitrates, molecules of the chemical form RONO2, are products of chain terminating reactions in the tropospheric HOx and NOx catalytic cycles and thereby impact ozone formation locally. Many of the molecules in the class have lifetimes that are long enough that they can be transported over large distances. If the RONO2 then decompose to deliver NOx to remote reg...

A novel, mild and convenient method for the nitrodecarboxylation of substituted cinnamic acid derivatives to their nitroolefins is achieved using a catalytic amount of CuCl (10 mol%) and tertbutyl nitrite (2 equiv.) as a nitrating agent in the presence of air. This reaction provides a useful method for the synthesis of β,β-disubstituted nitroolefin derivatives, which are generally difficult to ...

Layered LiNi0⋅8Co0⋅2O2 crystallizing in R –3m space group is synthesized by decomposing the constituent metal–nitrate precursors. Oxidizing nature of metal nitrates stabilizes nickel in +3 oxidation state, enabling a high degree of cation ordering in the layered LiNi0⋅8Co0⋅2O2. The powder sample characterized by XRD Rietveld refinement reveals < 2% Li–Ni site exchange in the layers. Scanning el...

For the purpose of this work an epiphytic lichen species, Hypogymnia physodes (L.)NyL, was used. Thalli of the lichen were treated with solutions of nitrate salts of heavy metals, including Zn(NO3)2, Cu(NO3)2, Pb(NO3)2, and Cd(NO3)2. To simulate the acid rain impact, pH of the metal mixture was lowered to pH 4, using Na2S2O5. Content of heavy metals was determined after a standard UV mineraliza...

The ability of calcium aluminate cement (CAC) to encapsulate toxic metals (Pb, Zn and Cu) was assessed under two curing conditions. Changes in the consistency and in the setting time were found upon the addition of the nitrates of the target metals. Both Pb and Cu caused a delay in CAC hydration, while Zn accelerated the stiffening of the mortar. Compressive strengths of the metal-doped mortars...

In this paper, we bring forward an effective strategy, solvothermal postsynthesis, to prepare ordered mesoporous silica materials with highly branched channels. Structural characterizations indicate that the titled mesoporous materials basically have the cubic double gyroidal (space group Ia-3d) structure with small fraction of distortions. The mesopore sizes and surface areas can be up to 8.8 ...