Metallocene-bridged [60]fullerene triads and cyclised metallocene-[60]fullerene diads are formed via [3 + 2] cycloaddition reactions of [60]fullerene with metallocene dialdehyde and an amino acid. In the case of cyclic diads only one regioisomer is formed, as determined by UV-vis and NMR spectroscopic studies. These compounds have both electron donor (metallocene) and acceptor ([60]fullerene) c...

Porous organic polymers (POPs) are widely used in various areas such as adsorption, separation and catalysis. In the present work, ionic liquid-modified porous (IL-POPs) synthesized by dispersion polymerization were applied to immobilize metallocene catalysts for olefin polymerization. The prepared IL-POPs characterized Fourier transform infrared spectrometer (FT-IR), nitrogen sorption porosime...

isotactic poly (1-butene), ipbu-1, was synthesized by using a metallocene catalyst. the thermodynamic phase behavior of polymer–organic solvents systems is very important in every polymer application.  in this paper, the solid–liquid equilibrium of ipbu-1 with different organic solvents (1-heptyne, cyclo octane) was studied by a mathematical model. by considering the experiments temperature-mol...

Bis(1-methylethenyl-cyclopentadienyl)zirconium dichloride (7a) was prepared by a fulvene route. Photolysis at 0 degrees C with Pyrex-filtered UV light resulted in a rapid and complete intramolecular [2+2]cycloaddition reaction to yield the corresponding cyclobutylene-bridged ansa-zirconocene dichloride isomer (8a). This is one of the rare examples of an organic functional group chemistry that l...

We synthesized polyethylene (PE), poly(ethylene-co-1-decene), poly(ethyleneco-p-methylstyrene) and poly(ethylene-ter-1-decene-ter-p-methystyrene) using a rac-Et(Ind)2ZrCl2 metallocene catalyst and a methylaluminoxane cocatalyst system. The materials were characterized using nuclear magnetic resonance spectroscopy and Fourier transform infrared spectroscopy. We compared and studied the kinetics,...

The performance profile of a supported metallocene catalyst in slurry-phase ethylene polymerisation can be significantly enhanced by tuning the chemical composition support. By employing supports derived from zinc-containing layered double hydroxides (LDHs), slurry phase productivity (EBI)ZrCl2 (EBI = rac-ethylenebis(indenyl)) quadrupled relative to magnesium-containing Productivity increases a...