glycerol mono-oleate (gmo) was produced by direct esterification reaction with amberlyst 16 resin catalysts with the efficiency of 86% and was used as a surfactant for synthesis of cofe2o4 nano-particles by surfactant-assisted microwave method. fourier transform infrared spectroscopy (ft-ir), x-ray diffraction (xrd) and scanning electron microscopy (sem) were used to consider the structural and...

Efforts are made in this thesis to reveal the dynamics of single-electron tunneling and to realize quantum bits (qubits) in semiconductor quantum dots. At low temperatures, confined single quantum dots and double quantum dots are realized in the twodimensional electron gas (2DEG) of AlGaAs/GaAs heterostructures. For transport studies, quantum dots are coupled to the drain and source contacts vi...

The formation of pure single crystalline silicon nanoparticles by microwave induced decomposition of silane in a low pressure flow reactor is reported. The morphology and crystal structure of the particles are characterized in situ by particle mass spectrometry (PMS) and ex situ by means of X-ray diffraction, high resolution transmission electron microscopy, electron energy loss spectroscopy, a...

In this study, reactions of quaternization under microwave heating of pyridine, α-picoline, pyridine-4-aldoxime, pyridine-2aldoxime, nicotinamide, isonicotinamide and pyridoxal oxime with different electrophiles: 2-bromo-4'-nitroacetophenone, 2-amino-4chloro-methylthiazole hydrochloride, methyl iodide, 1,3-diiodopropane and 1,3-dibromopropane are reported. The synthesis yield by microwave diele...

X-band microwave spectroscopy is applied to study the cyclotron resonance in Bi(2)Te(3) exposed to ambient conditions. With its help, intraband transitions between Landau levels of relativistic fermions are observed. The Fermi velocity equals to 3260 m/s, which is much lower than has been reported in the literature for samples cleaved in vacuum. Simultaneous observation of bulk Shubnikov-de Haa...

A series of Nـ alkyl 2ـ ketomethylquinoline derivatives were synthesis by reaction of benzoyl chloride derivatives with Nـ methyl quinaldine iodide in the presence of triethyl amine under microwave irradiation. Enaminone form of the product study by spectroscopy method. The result revealed the  Nـ alkyl 2ـ ketomethylquinoline the fixed enaminone tautomer.

A series of Nـ alkyl 2ـ ketomethylquinoline derivatives were synthesis by reaction of benzoyl chloride derivatives with Nـ methyl quinaldine iodide in the presence of triethyl amine under microwave irradiation. Enaminone form of the product study by spectroscopy method. The result revealed the  Nـ alkyl 2ـ ketomethylquinoline the fixed enaminone tautomer.

We present the first high-resolution rotational spectrum of an artificial molecular rotary motor. By combining chirped-pulse Fourier transform microwave spectroscopy and supersonic expansions, we captured the vibronic ground-state conformation of a second-generation motor based on chiral, overcrowded alkenes. The rotational constants were accurately determined by fitting more than 200 rotationa...

We report the use of in situ Raman spectroscopy as a probe for the effect of power on microwave-promoted Suzuki coupling reactions. We find that increased initial microwave power leads to greater acceleration of the reaction but that the product yield obtained is essentially independent of initial microwave power. The application of simultaneous cooling lengthens the reaction time but does not ...

In this study a special type of silicoaluminophosphate with opal structure (Opal-SAPO) was prepared under microwave condition using tetraethylorthosilicate (TEOS), triethanolamine (TEA), aluminiumisopropoxid and phosphoric acid 85%. The product was characterized by X-ray diffraction (XRD), thermogravimetric (TGA) and Fourier Infrared Spectroscopy (FTIR).The crystalline product showed a good act...