Light transducing phycobiliproteins are encapsulated in optically transparent sol-gel matrices. Absorption and fluorescence spectroscopies are used to characterize the effect of the sol-gel encapsulation on the conformation and aggregation states of the three major phycobiliproteins present in phycobilisomes: phycoerythrin, phycocyanin, and allophycocyanin. It is found that the effects of sol-g...

A glass-chip-based sample preparation method for matrix-assisted laser desorption/ionization mass spectrometric (MALDI-MS) analysis of tryptic digests of proteins and intact cells is described. A MALDI matrix, 2,5-dihydroxybenzoic acid (2,5-DHB), was hybridized with sol-gels to generate a sol-gel-derived material. Taking advantage of the characteristics of sol-gels, the sol-gel-derived material...

Many optics in both the OMEGA and OMEGA EP lasers are coated with anti-reflective (AR) silane sol-gel to maximize their transmittance. Although these coatings are highly resistant to both airborne contaminants and laser damage, they are susceptible to mechanical damage by abrasion, and thus require extra care during the handling, installation and alignment of sol-gel optics. Previous “hardened”...

Hydrothermally and sol-gel-synthesized immobilized surfactant-modified polyaniline-carbon nanotubes/TiO₂ (PANi-CNT/TiO₂) photocatalysts were prepared and their application in the degradation of diethyl phthalate (DEP) under visible light at 410 nm was investigated in this sturdy. To improve the dispersion of nanoparticles and the transfer of electrons, the TiO₂ surface was modified with both so...

in this research, we reported a novel modified carbon ceramic electrode (cce) using ni/al layered double hydroxide as modifier was fabricated by sol-gel technique. the ni/al layered double hydroxide modified sol gel derived carbon ceramic (ni/al ldh-sgd-cc) electrode was used for electrocatalytic oxidation of acetaldehyde. the oxidation of acetaldehyde happens at the potential where ni (iii) sp...

Sol-gel derived silica possess many promising features, including low-temperature preparation procedure, porosity, chemical and physical stability. Applications exploiting porous materials to encapsulate sensor molecules, enzymes and many other compounds, are developing rapidly. In this paper some potential applications, with emphasis on biomedical and environmental ones, are reviewed. The mate...