نتایج جستجو برای: modified voltammetric methods

تعداد نتایج: 2077917  

2015
Negussie Negash Hailemichael Alemu Merid Tessema

Screen printed carbon electrode (SPCE) has been modified with single wall carbon nanotube/poly(3,4-ethylenedioxythiophene) (SWCNT/PEDOT) composites for the determination of phenol and chlorophenols (phenol, 4-chlorophenol, 2,4-dichlorophenol, and 2,4,6-trichlorophenol). The effect of the modifiers on the electrode characteristics was evaluated and the responses were optimized for the voltammetr...

Journal: :Talanta 2009
Dong-Mei Wu Guang-Lei Fu Hong-Zhuang Fang Ling Hu Jin-Lian Li Xing Yuan Zhuo-Yong Zhang

A novel experimental method was developed to study the origin of the voltammetric response of human prostate cancer (PC-3) cell suspension as a model in consideration of the biological characters of living cells. The presence of guanine and xanthine in the cell eluent secreted by the living cells was verified by HPLC assay with a DAD system and chemometric method. Comparative studies of voltamm...

Journal: :The Analyst 1997
A M Yu H L Zhang H Y Chen

Cyclic voltammetry was undertaken to investigate the electrochemical behavior of uric acid at a polyglycine modified electrode. The modified electrode shows catalytic ability for the oxidation of uric acid, reducing the overpotential by 250 mV in pH 7.0 phosphate buffer solution. The enhanced voltammetric response can be used to determine uric acid. The linear range is between 5.0 x 10(-8) and ...

Journal: :Bioinorganic Chemistry and Applications 2005
Ivana Šestáková Tomáš Navrátil

The application of voltammetric methods using different rates of polarisation on HMDE reveal inert or labile behaviour of Cd- or Zn- complexes in the presence of excessive cadmium or zinc ions in solution. This phenomenon was demonstrated first on the simplest phytochelatin - complex of peptide (gamma-Glu-Cys)(2) Gly with cadmium, later on rabbit liver metallothioneins - Cd(7) MT in the presenc...

The electrocatalytic oxidation of captopril (CAP) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ISPT) using cyclic voltammetry (CV), chronoamperometry and square wave voltammetry (SWV). Also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for CAP were calculated. The mechanism of CA electrochemical behavior at the mo...

Journal: :Materials advances 2023

Herein, we present the fabrication of an N ′, ′′, ′′′, ′′′′-tetra(salicylidene)-amino benzene-modified multi-walled carbon nanotube electrode (TSAB/MWCNT) for voltammetric determination Pb 2+ and Cd .

2007
Vahid Nasiri Hassan Karimi-Maleh Mohammad A. Khalilzadeh Daryoush Zareyee

In this work, we study electrochemical behavior of p-chloranil as a suitable mediator for voltammetric determination of dopamine (DA) using voltammetric method. Using the modified electrode, the kinetics of DA electrooxidation was considerably enhanced by lowering the anodic over potential through a catalytic fashion. The differential voltammetric peak currents of the electrode increased linear...

Journal: :Chemical communications 2012
Julio C Zuaznabar-Gardona Roberto Cao Roberto Cao Margarita Suarez

Multiwalled carbon nanotubes modified with 2-aminoethanethiol (MWNT-AET) were vertically self-assembled on gold electrodes with the assistance of chitosan and Tween. According to AFM and cyclic voltammetric determinations the best results were achieved using chitosan.

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