نتایج جستجو برای: modified voltammetric methods
تعداد نتایج: 2077917 فیلتر نتایج به سال:
Screen printed carbon electrode (SPCE) has been modified with single wall carbon nanotube/poly(3,4-ethylenedioxythiophene) (SWCNT/PEDOT) composites for the determination of phenol and chlorophenols (phenol, 4-chlorophenol, 2,4-dichlorophenol, and 2,4,6-trichlorophenol). The effect of the modifiers on the electrode characteristics was evaluated and the responses were optimized for the voltammetr...
A novel experimental method was developed to study the origin of the voltammetric response of human prostate cancer (PC-3) cell suspension as a model in consideration of the biological characters of living cells. The presence of guanine and xanthine in the cell eluent secreted by the living cells was verified by HPLC assay with a DAD system and chemometric method. Comparative studies of voltamm...
Cyclic voltammetry was undertaken to investigate the electrochemical behavior of uric acid at a polyglycine modified electrode. The modified electrode shows catalytic ability for the oxidation of uric acid, reducing the overpotential by 250 mV in pH 7.0 phosphate buffer solution. The enhanced voltammetric response can be used to determine uric acid. The linear range is between 5.0 x 10(-8) and ...
The application of voltammetric methods using different rates of polarisation on HMDE reveal inert or labile behaviour of Cd- or Zn- complexes in the presence of excessive cadmium or zinc ions in solution. This phenomenon was demonstrated first on the simplest phytochelatin - complex of peptide (gamma-Glu-Cys)(2) Gly with cadmium, later on rabbit liver metallothioneins - Cd(7) MT in the presenc...
The electrocatalytic oxidation of captopril (CAP) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ISPT) using cyclic voltammetry (CV), chronoamperometry and square wave voltammetry (SWV). Also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for CAP were calculated. The mechanism of CA electrochemical behavior at the mo...
Herein, we present the fabrication of an N ′, ′′, ′′′, ′′′′-tetra(salicylidene)-amino benzene-modified multi-walled carbon nanotube electrode (TSAB/MWCNT) for voltammetric determination Pb 2+ and Cd .
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In this work, we study electrochemical behavior of p-chloranil as a suitable mediator for voltammetric determination of dopamine (DA) using voltammetric method. Using the modified electrode, the kinetics of DA electrooxidation was considerably enhanced by lowering the anodic over potential through a catalytic fashion. The differential voltammetric peak currents of the electrode increased linear...
Multiwalled carbon nanotubes modified with 2-aminoethanethiol (MWNT-AET) were vertically self-assembled on gold electrodes with the assistance of chitosan and Tween. According to AFM and cyclic voltammetric determinations the best results were achieved using chitosan.
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