A facile synthesis of a styrylpyridinium salt (SbQ)/montmorillonite (MMT) via cationic exchange interactions between styrylpyridinium species (specifically SbQ) and MMT platelets is reported in this work. The SbQ-MMT solutions were irradiated under ultraviolet (UV) light for a specific time to obtain the cross-linked SbQ-MMT materials. Scanning electron microscopy and atomic force microscopy an...

Three different protocols for the preparation of polymer layered silicate nanocomposites based upon a tri-functional epoxy resin, triglycidyl para-amino phenol (TGAP), have been compared in respect of the cure kinetics, the nanostructure and their mechanical properties. The three preparation procedures involve 2 wt% and 5 wt% of organically modified montmorillonite (MMT), and are: isothermal cu...

In this work, maghemite intercalated montmorillonite (γFe₂O₃-MMT)/polymer nanocomposites loaded with 1 or 2 wt.% of nanofillers were obtained by photopolymerization of difunctional acrylate monomers. The γFe₂O₃-MMT nanofillers were prepared by a new method based on the in situ formation of maghemite in the interlayer space of Fe-MMT using a three step process. X-ray diffraction (XRD), chemical ...

A novel bio nanocomposite of Carboxymethyl Starch (CMS)-Chitosan (CS)-Montmorillonite (MMT) was developed for Curcumin delivery. To improve Curcumin entrapment into Cs-CMS-MMT, different ratios of Chitosan (Cs), Carboxymethyl Starch (CMS) and MMT were used. Particle size and Curcumin entrapment efficiency (EE) were highly affected by different formulation variables. Polysaccharide concentration...

Our continuing research on the preparation, characterization, materials properties, and biodegradability of polylactide (PLA)/organically modified layered silicate (OMLS) nanocomposites has yielded results on PLA/montmorillonite nanocomposites. Montmorillonite (mmt) modified with dimethyldioctadecylammonium cation was used as an OMLS for nanocomposite preparation. The internal structure of nano...

Montmorillonite/poly(vinyl alcohol) (MMT/PVA) nanocomposites spanning the complete range of MMT content (0-100 wt%) are prepared by simple evaporation-induced assembly. Effects of MMT content on the structure and mechanical properties of nanocomposites are systematically investigated and exhibit two important transitions at MMT contents of 30 wt% and 70 wt%. In the range of 0-30 wt%, the nanoco...

novel citric acid modified starch-carboxy methyl cellulose (cmc) -montmorillonite (mmt) bionanocomposite films were prepared by casting method and the effect of mmt on the structural and physical properties of the starch-cmc biocomposites was studied. x-ray diffraction test showed thatstrong polar interactions between the hydroxyl groups present in the starch and cmc chains and in the silicate ...

Polypropylene/Multiwall carbon nanotubes/Montmorillonite (PP/MWNTs/MMT) hybrid nanocomposites were prepared by using twin-screw extruder incorporating the polypropylene grafted maleic anhydride (PP-g-mA) as compotibilizer is used for better dispersion of nanoclay in the polymer matrix. The effect of MWNTs and MMT on the polypropylene matrix was investigated in terms of mechanical properties of ...

The potential use of nanoclay was examined to modify fluid transfer properties of medium density fiberboard (MDF). For this, Na+ montmorillonite (Na+MMT) nanoclay was added to urea formaldehyde resin to produce MDF. Then, the air permeability and mass diffusivity of MDF were evaluated. Scanning electron microscope (SEM) images and X-ray diffraction (XRD) confirmed a dispersion and exfoliation o...

The effect of organomodified montmorillonite (MMT) content and mixing conditions on the mechanical properties, structure, morphology a chloroprene rubber was investigated. Nanoparticles were mechanically mixed with plasticizer, followed by ultrasonic homogenization before compounding all ingredients mixtures in two-roll mills. Mechanical tests carried out samples prepared three sonication ampli...