Motivated by Yung and Miller’s suggestion [1997] that N2O is isotopically fractionated during UV photolysis in the stratosphere, we have studied the photolysis rates of the NNO and NNO structural isotopomers. In this study, we follow the concentrations of these compounds with FTIR spectroscopy during photolysis at 213 nm. Our results show that, as Yung and Miller predicted, the photolysis rate ...
