[1] Although the oceans are a significant source of the greenhouse gas nitrous oxide (N2O) to the atmosphere, the magnitude and characteristics of this source are poorly constrained. We present here stable isotope and isotopomer (intramolecular distribution of N within the linear NNO molecule) results for N2O and oxygen stable isotopic data for dissolved O2 from Station ALOHA in the subtropical...

Rising concentrations of nitrous oxide (N2O) in the atmosphere are causing widespread concern because this trace gas plays a key role in the destruction of stratospheric ozone and it is a strong greenhouse gas. The successful mitigation of N2O emissions requires a solid understanding of the relative importance of all N2O sources and sinks. Stable isotope ratio measurements (δ15N-N2O and δ18O-N2...

The emission of greenhouse gases, such as N2O, from wastewater treatment plants is a matter of growing concern. Denitrification by ammonia-oxidizing bacteria (AOB) has been identified as the main N2O producing pathway. To estimate N2O emissions during biological nitrogen removal, reliable mathematical models are essential. In this work, a mathematical model for NO (a precursor for N2O formation...

[1] We report original data on nitrous oxide (N2O) fluxes from two tropical reservoirs, their rivers below the dam, and from natural aquatic ecosystems and rainforest soils in French Guiana and Panama. We also review published N2O fluxes from other tropical reservoirs and natural environments. We show that: (1) N2O emissions from tropical reservoirs occur mainly at the reservoir surface, fluxes...

In the tropics, termites are major players in the mineralization of organic matter leading to the production of greenhouse gases including nitrous oxide (N2O). Termites have a wide trophic diversity and their N-metabolism depends on the feeding guild. This study assessed the extent to which N2O emission levels were determined by termite feeding guild and tested the hypothesis that termite speci...

The nitrous oxide emissions were measured at three tundra sites and one snowpack on the Fildes Peninsula in the maritime Antarctic in the summertime of 2002. The average fluxes at two normal tundra sites were 1.1+/-2.2 and 0.6+/-1.7 microg N2O m(-2)h(-1), respectively. The average flux from tundra soil site with penguin dropping addition was 3.7+/-2.0 microg N2O m(-2)h(-1), 3-6 times those from...

Nitrous oxide (N2O) is a trace gas that contributes to the greenhouse effect and stratospheric ozone depletion. The N2O yield from nitrification (moles N2O-N produced per mole ammonium-N consumed) has been used to estimate marine N2O production rates from measured nitrification rates and global estimates of oceanic export production. However, the N2O yield from nitrification is not constant. Pr...

Our purpose was to measure simultaneous fluxes from soil of both N2O and N2 from the same plot in the field using the 15N-gas "nonequilibrium" technique (i.e., the "Hauck" technique) as used previously for N2. We accommodated analysis of N2O by modifying the head amplifier of our mass spectrometer. Our system accurately measured the 15N enrichments of labeled soil slurries for both N2 and N2O. ...

Denitrification is mediated by microbial, and physicochemical, processes leading to nitrogen loss via N2O and N2 emissions. Soil pH regulates the reduction of N2O to N2, however, it can also affect microbial community composition and functional potential. Here we simultaneously test the link between pH, community composition, and the N2O emission ratio (N2O/(NO + N2O + N2)) in 13 temperate past...

Both plant invasion and nitrogen (N) enrichment should have significant impact on mangrove ecosystems in coastal regions around the world. However, how N2O efflux in mangrove wetlands responds to these environmental changes has not been well studied. Here, we conducted a mesocosm experiment with native mangrove species Kandelia obovata, invasive salt marsh species Spartina alterniflora, and the...