In this study at first , an azo dye, 2,7- naphthalenediol, 2-[(4-Bromophenyl)azo (BPAND) as a ligand has been synthesized by addition of p-Bromoaniline to the modified montomorillonite K10 clay. This ligand was characterized using 1H-NMR, UV-Vis and IR spectroscopies. Subsequently, its interaction with calf thymus deoxyribonucleicacid ,ct-DNA was investigated in 5 mM phosphate buffer solution, ...

the interaction of fe2+ ion with pyrazole was theoretically studied by gussian 03, software at hf/(lanl2dz+6-31g) and hf/ (lanl2dz+6-31g (d)) levels in gas phase and solution. in this study acompartion between optimized structures of pyrazole molecule in aspect of thermodynamicparameters such as enthalpy (h°), gibbs free energy (g°) and entropy (s°) in presence of metallic ion(fe2+), was perfor...

The phonon densities of states for pure vanadium and the solid solutions V-6.25% Ni, Pd, Pt were determined from inelastic neutron scattering measurements. The solute atoms caused a large stiffening of the phonons, resulting in large, negative vibrational entropies of mixing. For V-6.25%Pt, the negative vibrational entropy of mixing exceeds the conventional positive chemical entropy of mixing. ...

A grand challenge in the field of artificial life is to find a general theory of emergent self-organizing systems. In this paper we try to explain the emergent behavior of a simulated swarm by applying methods based on the fluctuation theorem. Empirical results indicate that the swarm is able to produce negative entropy within an isolated sub-system due to ‘frozen accidents’. Individuals of the...

Negative absolute temperatures were introduced into experimental physics by Purcell and Pound, who successfully applied this concept to nuclear spins; nevertheless the concept has proved controversial : a recent article aroused considerable interest by its claim, based on a classical entropy formula (the ‘volume entropy’) due to Gibbs, that negative temperatures violated basic principles of sta...