Aromatic nitriles are prepared efficiently through transition-metal-mediated cyanation of aryl (pseudo)halides with metallic cyano-group sources, such as CuCN, KCN, NaCN, Zn(CN)(2), TMSCN, or K(4) [Fe(CN)(6)]. However, this approach often suffers from drawbacks, such as the formation of stoichiometric amounts of metal waste, the poisoning of the metal catalysts, or the generation of toxic HCN g...

Magnetic resonance imaging is an important technique for identifying different types of tissues in a body or spatial information about composite materials. Because temperature is a fundamental parameter reflecting the biological status of the body and individual tissues, it would be helpful to have temperature maps superimposed on spatial maps. Here we show that small ferromagnetic particles wi...

The composite photocatalyst can be constructed by using natural porous minerals with a wide range of sources, low prices and stable chemical properties as the titanium dioxide catalyst carrier, which not only reduce cost preparation application, but also effectively improve dispersion, recyclability catalytic performance catalyst. In recent years, large number scientific researchers have conduc...

This Article explores the idea of using nonmetallic contacts for molecular electronics. Metal-free, all-carbon molecular electronic junctions were fabricated by orienting a layer of organic molecules between two carbon conductors with high yield (>90%) and good reproducibility (rsd of current density at 0.5 V <30%). These all-carbon devices exhibit current density-voltage (J-V) behavior simila...

Material stocks are an important part of the social metabolism. Owing to long service lifetimes of stocks, they not only shape resource flows during construction, but also during use, maintenance, and at the end of their useful lifetime. This makes them an important topic for sustainable development. In this work, a model of stocks and flows for nonmetallic minerals in residential buildings, ro...

A modification of the polyol process has enabled the direct synthesis of nm-sized Ag particles with narrow size distribution and controlled average dimension embedded in a polymeric matrix. Dispersion of colloidal silver was obtained by reduction of silver nitrate in ethylene-glycol in the presence of a polymeric protective agent (i.e., poly(N-vinylpyrrolidone)) and ultrasounds. The final parti...

Designing an apparatus for experiments that operate deep into the milliKelvin regime requires a careful selection of materials and construction techniques, and often entails balancing mutually contradictory requirements. In the case of magnetic susceptibility measurements, this involves choosing materials that realize both high thermal conductivity for good heat sinking and low electrical condu...

The importance of friction and wear control cannot be over emphasized for economic reasons and longterm reliability. The savings can be substantial, and these savings can be obtained without the deployment of investment. Tribology is crucial to modern machinery which uses sliding and rolling surfaces. This article describes the tribological behavior analysis for the conventional materials i.e. ...