Soft lithography was used to replicate nanoscale features made using electron beam lithography on a polymethylmethacrylate (PMMA) master. The PMMA masters were exposed to fluorinated silane vapors to passivate its surfaces so that polydimethylsiloxane (PDMS) did not permanently bond to the master. From scanning electron microscopy, the silanization process was found to deposit a coating on the ...

Fluid control is a key element in the performance of microfluidic “lab-on-a-chip” devices. The development of integrated multi-function micro-chemical reactors and analysis platforms depends upon on-chip valving and pumping. In this work, microfluidic valves and pumps were fabricated from etched glass substrates each bonded to a second glass substrate lid that had ultrasonically drilled access ...

Recent U.S. government action to lower the maximum concentration levels (MCL) of total arsenic (As) (10 ppb) in drinking water has raised serious concerns about the agricultural use of As-containing biosolids such as poultry litter (PL). In this study, solid-state chemical speciation, desorbability, and total levels of As in PL and long-term amended soils were investigated using novel synchrotr...

OBJECTIVES To evaluate the effect of silane application and silane heat treatment on lithium-disilicate ceramic when bonded to composite resin. METHODS Twelve blocks of lithium-disilicate (LD) ceramic were fabricated and bonding surfaces were etched using 9.5% hydrofluoric acid (90 seconds). Three experimental groups resulted from the various surface treatment combinations, which included, no...

We view the structures and features described in this atlas as sedimentary structures, albeit of a complex organo-physico-chemical origin. Just like their physical sedimentary structure counterparts (e.g., Pettijohn and Potter, 1964), they can be of great assistance in unravelling depositional palaeoenvironments inferred for ancient rock successions. Pettijohn and Potter (1964) included stromat...

OBJECTIVE The aim of this study was to investigate the effect of silane in the repair of old and new resin-composite restorations. METHOD Part 1: repair of old composite was performed on 60 resin-composite substrates that were 6 years old and were made of six different brands of composite. Three experiments were performed. In the first experiment, the substrates were ground flat and composite...

When we think of chlorine, we often relate it to the salt used in food preparation, chloride in the oceans, chlorine gas from swimming pools, and gaseous chlorofluorocarbons that have close links to the depletion of stratospheric ozone. We rarely think of thousands of chlorinated hydrocarbons that exist in the natural systems, several of which are highly toxic to humans (1). The C-Cl bond, comm...

Inorganic semiconductor ferroelectrics such as BiFeO3 have shown great potential in photovoltaic and other applications. Currently, semiconducting properties and the corresponding application in optoelectronic devices of hybrid organo-plumbate or stannate are a hot topic of academic research; more and more of such hybrids have been synthesized. Structurally, these hybrids are suitable for explo...

Photoinitiated silane-ene chemistry has the potential to pave the way toward spatially resolved organosilicon compounds, which might find application in biomedicine, microelectronics, and other advanced fields. Moreover, this approach could serve as a viable alternative to the popular photoinitiated thiol-ene chemistry, which gives access to defined and functional photopolymer networks. A difun...