A protocol for the coupling of potassium xanthogenates with ?-(trifluoromethyl)styrenes in presence triethyl phosphite is reported. The reaction carried out under blue light irradiation organic photocatalyst 3DPAFIPN. proceeds via formation alkyl radicals from readily available xanthogenate salts oxidative desulfurization and cleavage carbon–oxygen bond assisted by phosphite.

Different strains of Thiobacillus ferrooxidans and Thiobacillus thiooxidans were used to catalyze the oxidative dissolution of iron pyrite, FeS(2), in nine different coal samples. Kinetic variables and parametric factors that were determined to have a pronounced effect on the rate and extent of oxidative dissolution at a fixed Po(2) were: the bacterial strain, the nitrogen/phosphorus molar rati...

The micro morphology of limestone sorbent is a key for improving the SO2 removal efficiency in the coal-fired power plant. The tube furnace system was built for imitating the indirect desulfurization reaction in traditional boiler atmosphere (65%N2, 15%CO2, 4.7%O2, 15%H2O, 0.3%SO2) and the direct desulfurization reaction in oxygen-fired atmosphere (80%CO2, 4.7%O2, 15%H2O, 0.3%SO2). The reacted ...

The purpose of this study was to investigate the reuse of desulfurization slag in cement clinker production and its influence on the formation of clinker phases. The desulfurization slag that mainly contained Ca and Si was identified as non-toxic, and thus it should be suitable to be reused in clinker production. The addition of desulfurization slag increased the melt phase during clinkerizatio...

Dibenzothiophene (DBT), benzothiophene (BT) and thiophene (T) were catalytically oxidized to their corresponding sulfone products by H2O2 in the presence of magnetically recoverable polyoxometalate-based nano catalyst. Different extracting solvents including ethanol, acetonitrile, and dimethylformamide were tested. The best results were obtained by ethanol extraction. The oxidative desulfurizat...

In this work, an N-butyl-pyridinium-based ionic liquid [BPy]BF(4) was prepared. The effect of extraction desulfurization on model oil with thiophene and dibenzothiophene (DBT) was investigated. Ionic liquids and hydrogen peroxide (30%) were tested in extraction-oxidation desulfurization of model oil. The results show that the ionic liquid [BPy]BF(4) has a better desulfurization effect. The best...

In making the gas-solid-liquid phase analysis, based on the collaborative study of the internal and external humidification ratio of desulfurization efficiency, determine the humidifier ratio within 60% to 75%, that can make the best balance between the respective merits of a simple tower humidifiers tower humidifier way, optimizing the overall desulfurization reaction, effectively reducing the...

In this research work, thar coal was treated with NaOH solution in dissolved oxygen different reaction parameters an isothermal reactor. All three types of sulfur were removed from through oxidative alkali leaching under pressure. About 90% pyretic sulfur, 78% organic and 50% sulfate removed, more than 82% total removal achieved. Effects various observed, it investigated that time, agitation sp...