A central issue in the equation of state (EoS) development is to describe accurately fluid density and thus other thermodynamic properties based on it. This study attempts investigate modeling high-pressure mixtures, particularly related reservoir fluids, by cubic non-cubic EoS. large database binary mixtures petroleum fluids was established used compare some typical EoS, including SRK, PR, PC-...

A mathematical model for polymerization kinetics and molar mass development in the nitroxide-mediated (NMP) of vinyl monomers supercritical carbon dioxide (scCO2) has been developed. The method moments is used development. perturbed-chain statistical associating fluid theory (PC-SAFT) equation state to estimate number stable phases present at equilibrium reaction mixture, critical average chain...

A continuous flow apparatus was applied to measure the phase equilibrium at 523 K and 573 K. The performance of analysed with determination vapor pressures water temperatures ( T = 453 473 K). measured deviated from literature values less than 1 %. Vapor n -dodecane, -hexadecane phenol were 523–623 K) and, bubble point -dodecane + pure components compared values. Relative pressure value 2 % for...

In B-mode imaging, lateral resolution is impeded by the size and shape of the ultrasound beam used to create the image. For improved lateral resolution, a focussing method that utilises a beam model calculated using the Fraunhofer far field approximations to enhance the Synthetic Aperture Focussing Technique (SAFT) is proposed. The Beam Model Weighted Synthetic Aperture Focussing Technique (BMW...

We have developed a “global” crossover (GC) statistical associating fluid theory (SAFT) equation of state (EOS) for associating fluids that incorporates nonanalytic scaling laws in the critical region and in the limit of low densities, F f 0, is transformed into the ideal-gas equation EOS. Unlike the crossover SAFT EOS developed earlier, the new GC SAFT EOS contains a so-called kernel term and ...

In this work the solubility of 15 amino acids and 18 peptides in aqueous 2-propanol solutions was successfully modelled using PC-SAFT that used recently determined experimental melting properties as input data.

The suitability of phenyl-based deep eutectic solvents (DESs) as absorbents for toluene absorption was investigated by means thermodynamic modeling and molecular dynamics (MD). models perturbed-chain statistical associating fluid theory (PC-SAFT) conductor-like screening model real (COSMO-RS) were used to predict the vapor–liquid equilibrium DES–toluene systems. PC-SAFT yielded quantitative res...

In this paper, we present a systematic review of the perturbed-chain statistical associating fluid theory equation state (PC-SAFT) EoS for thermodynamic modeling with application in asphaltene phase behavior simulation. The SAFT and its modified version known as PC-SAFT is briefly introduced. Then, uses tool highlighted. Crude oil characterization methods procedures are described focus on SARA-...

Abstract This research study aims to conduct a comparative performance analysis of different scaling equations and non-scaling models used for modeling asphaltene precipitation. The experimental data carry out this are taken from the published literature. Five which include Rassamadana et al., Rassamdana Sahimi, Hu Gou, Ashoori log–log were applied in two ways, i.e., on full dataset partial dat...