In this work, poly (ether-block-amide) (PEBA)/ceramic hollow fiber (HF) composite membranes with high flux were prepared by dip-coating the ceramic hollow fiber with PEBA polymer solution for pervaporation (PV). The membrane fabrication was optimized by finely tailoring the coating parameters such as the viscosity and concentration of PEBA coating solution, which made the pervaporation flux as ...

As a new family of two-dimensional (2D) materials, MXene, with many attractive physicochemical properties, has attracted increasing attentions and been applied for various applications. Here, for the first time, ultrathin MXene membranes with thickness down to several tens of nanometers were developed for pervaporation desalination by stacking synthesized atomic-thin MXene nanosheets. Influence...

We present a theoretical model for the evolution of mixture concentrations in a micro-pervaporation device, similar to those recently presented experimentally. The described device makes use of the pervaporation of water through a thin PDMS membrane to build up a solute concentration profile inside a long microfluidic channel. We simplify the evolution of this profile in binary mixtures to a on...

The framework of non-equilibrium thermodynamics (NET) is used to derive heat and mass transport equations for pervaporation of a binary mixture in a membrane. In this study, the assumption of equilibrium of the sorbed phase in the membrane and the adjacent phases at the feed and permeate sides of the membrane is abandoned, defining the interface properties using local equilibrium. The transport...

A solution--diffusion model for the permeation of liquid mixtures through polymeric membranes taking into account coupling of fluxes has been developed. The model is applied to the separation by pervaporation of ethanol-water mixtures through cellulose acetate. In order to determine the activities of the permeating components in the polymeric membrane, values of polymer-liquid and liquid---liqu...

In this article, the pervaporation selectivity as a function of the membrane thickness is studied for the dehydration of acetic acid. From this study, it appeared that the selectivity of polysulfone (PSF) , poly (vinyl chloride) (PVC ) , and polyacrylonitrile (PAN) decreases with decreasing membrane thickness, below a limiting value of about 15 pm. However, in the case of gas separation, the se...

Dense flat-sheet membranes were prepared from poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) using the casting solvents chloroform and 1,1,2-trichloroethylene. X-ray diffraction, tapping mode atomic force microscopy (TM-AFM), and contact angle studies were used to characterize the membranes. The surface energy and the solubility parameters of the PPO membranes were determined from the measured co...

Increasing the hydrophobicity of membrane was believed as an effective approach to enhance the performance of organophilic pervaporation (PV) membrane. In this work, the superhydrophobic alkyl group modificated metal organic framework (MOF) of RHO-[Zn(eim)2] (MAF-6) was incorporated into polydimethylsiloxane (PDMS) polymer to fabricate mixed matrix membranes (MMMs). The morphologies, physical a...

This work focuses on modelling, simulation and process analysis of hybrid membrane separations namely on distillation and pervaporation. Such hybrid process can be applied for the separation of multicomponent azeotropic mixtures without the use of entrainer. Its application is illustrated by the separation of a non-ideal ternary mixture of acetone, isopropanol and water. The extended abstract d...