Each different molecular elemental composition-e.g., C(c)H(h)N(n)O(o)S(s)-has a different exact mass. With sufficiently high mass resolving power (m/Deltam(50%) approximately 400,000, in which m is molecular mass and Deltam(50%) is the mass spectral peak width at half-maximum peak height) and mass accuracy (<300 ppb) up to approximately 800 Da, now routinely available from high-field (>/=9.4 T)...

OBJECTIVE Our objective was to investigate the association between head and neck cancer and occupational exposure to chlorinated, oxygenated and petroleum solvents in women. METHODS Investigation of occupational and environmental CAuses of REspiratory cancers (ICARE), a French population-based case-control study, included 296 squamous cell carcinomas of the head and neck (HNSCC) in women and ...

Density is one of the most prevalent physical property used to classify and characterise fluids, not only in the environmental, cosmetics, pharmaceuticals, and food and beverage industries, but also in hydrocarbon processing industry (HPI). Petroleum products are everywhere in today’s life, and have become almost natural parts of the modern world. Numerous products used on a daily basis are der...

Microbial fermentation is emerging as an increasingly important resource for the production of fatty acids to serve as precursors for renewable diesel as well as detergents, lubricants and other industrial chemicals, as an alternative to traditional sources of reduced carbon such as petroleum. A major disadvantage of fuels derived from biological sources is their undesirable physical properties...

Contamination of soil and groundwater by petroleum-based products is an extremely widespread and important environmental problem. Here we have tested a simple optical approach for detecting and identifying such industrial contaminants in soil samples, using a set of fluorescent DNA-based chemosensors in pattern-based sensing. We used a set of diverse industrial volatile chemicals to screen and ...

Petroleum-derived compounds, including polycyclic aromatic hydrocarbons (PAHs), commonly occur as complex mixtures in the environment. Recent studies using the zebrafish experimental model have shown that PAHs are toxic to the embryonic cardiovascular system, and that the severity and nature of this developmental cardiotoxicity varies by individual PAH. In the present study we characterize the ...

The Ludwig-Soret effect (that is, thermal diffusion) describes the concentration gradient in a mixture under a temperature gradient. The effect is quantified by the Soret coefficient, which is in turn related to the molecular and thermal diffusion coefficients of a mixture. Thermal diffusion is important in a myriad of applications, such as in petroleum reservoirs, material sciences, oceanograp...

Two continuous mixture phase equilibrium algorithms which can be used for vapor-liquid equilibrium calculation involving verymany-component fluid mixtures are proposed. The algorithms are applied to the case of simulated gas-condensate systems with analytical results. The proposed continuous mixture techniques reduce the required computer time significantly While they retain accuracy of the pre...

in the present work, the integral equations method is used to calculate transport properties of polar fluids. for this goal, we use the stockmayer potential and examine theoretically the thermal conductivity of several refrigerant mixtures such as r125+r134a, r125+r32, r125+r152a, r134a+r32, r152a+r32, r134a+r143a, and r125+r143a. we solve numerically the ornstein-zernike (oz) equation using th...