A quantum yield of •i•e = 2.3 x 10 '4 (+_ 4 X 10 -•) was determined for the photochemical degradation of 4nitrophenol over the wavelength range of 300 to 370 nm in ice pellets (pH 5.6). Five reaction products were identified: hydroquinone, benzoquinone, 4-nitrosophenol, nitrate, nitrite, and the likely formation of organic polymers. The similarities of these results to the observations from 4-n...

Sonolysis and photochemical degradation of different compounds such as chlorinated aliphatic hydrocarbons are among the recent advanced oxidation processes. Perchloroethylene is one of these compounds that has been mainly used as a solvent and degreaser. In this work, elimination of perchloroethylene in aqueous solution by ultrasonic irradiation, andphotochemical oxidation by ultra violet ray a...

The resource intensive human activities (such as mining and extraction of mineral oils for betterment of life and modernization of society) have increased environmental pollution several folds. Products of mining and petrochemical industries are advantageous for the modern society. But waste generated such as BTEX from such industries are carcinogenic, toxic and causes adverse effects on enviro...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

Visible-light-activated photochemical degradation against VOCs in indoor air using TiO 2 nanoparticles encapsulated crystal violet.

Iron(III) cross-linked alginate hydrogel incorporating sodium lactate undergoes photoinduced degradation, thus serving as a biocompatible positive photoresist suitable for photochemical patterning. Alternatively, surface etching of iron(III) cross-linked hydrogel contacting lactic acid solution can be used for controlling the thickness of the photochemical pattering. Due to biocompatibility, bo...

Advanced Oxidation Processes (AOP) using ozone, H2O2, ultrasound (US), ultraviolet radiation (UV), Fenton’s reagent (FeII+H2O2) alone or in combination involving hydroxyl radicals are considered as possible methods of clean and ecologically safe remedial treatment for the degradation of organics. In the present study, comparison of kinetics of photochemical, sonochemical and chemical oxidation ...

the objective followed in this study was to investigate the transport and degradation of herbicides under different herbigation vs. conventional spraying systems in soil. metribuzin and potassium bromide (kbr) were applied in soil plots by four application methods, including conventional spraying without delay in initial irrigation (cs1), conventional spraying with an initial 24-h delay in irri...