A model of interface induction for interlayer growing is proposed for bandgap engineering insights into photocatalysis. In the interface of CdS/ZnS core/shell nanorods, a lamellar solid solution intermediate with uniform thickness and high crystallinity was formed under interface induction process. Merged the novel charge carrier transfer layer, the photocurrent of the core/shell/shell nanorod ...

Nanocrystallite aggregates are spherical assemblies of nanometer-sized crystallites and feature a size on the order of sub-micrometers. This paper reports and summarizes recent progress in nanocrystallite aggregates for applications in dye-sensitized solar cells. It emphasizes that nanocrystallite aggregates are a promising class of materials with the capability to generate light scattering, en...

Hierarchical anatase TiO(2) nano-architecture arrays consisting of long TiO(2) nanowire trunk and numerous short TiO(2) nanorod branches on transparent conductive fluorine-doped tin oxide glass are successfully synthesized for the first time through a facile one-step hydrothermal route without any surfactant and template. Dye-sensitized solar cells based on the hierarchical anatase TiO(2) nano-...

We report on the synthesis of ZnO nanocrystallite aggregates in the presence of lithium ions and films consisting of these aggregates for dye-sensitized solar cell applications. A maximum overall conversion efficiency of 6.1% has been achieved with these films. This value is much higher than the 4.0% obtained for the films that are comprised of ZnOaggregates synthesized in the absence of lithiu...

We fabricated a Li doped CuO photoelectrode by doping with to improve the photoelectrochemical properties of photoelectrode. The was optimized experimentally investigating concentration, annealing temperature, and spin coating deposition cycle. It confirmed that had increased light absorption, decreased energy band gap, improved crystallinity. Li-doped porous surface, unlike bare photoelectrode...

A novel deoxyribose nucleic acid (DNA)-based photoelectrode consisting of DNA@Mn3(PO4)2 nanoparticles on graphene oxide (GO) sheets was successfully fabricated for photoelectrocatalysis. DNA served as a soft template to guide the nucleation and growth of Mn3(PO4)2 nanoparticles in the synthesis of Mn3(PO4)2 nanoparticles. More importantly, the DNA also serves as semiconductor materials to adjus...

ont matter & 2012 0.1016/j.nanoen.2 thor. s: chldwang@mail .edu (G. Cao). Abstract A novel interface precipitation method has been developed to synthesize hierarchically structured ZnO nanocrystallite aggregates. Such synthesized ZnO nanocrystallite aggregates were demonstrated as a promising structure for high power conversion efficiency when used as photoelectrode in dye-sensitized solar cell...

This communication describes a highly stable ZnO/Ta2O5 photoanode with Ta2O5 deposited by atomic layer deposition. The ultrathin Ta2O5 protective layer prevents corrosion of ZnO and reduces surface carrier recombination, leading to a nearly two-fold increase of photo-conversion efficiency. The transparency of Ta2O5 to sunlight is identified as the main reason for the excellent stability of the ...

Aligned CuO nanowires (NWs) were synthesized by a simple cost-effective oxidation method. They act as cores; high density CuO/ZnO core/shell heterostructure NWs were fabricated by thermal decomposition. Using the core/shell heterostructure NWs as a photoelectrode, a 0.71% photo-to-hydrogen conversion efficiency was obtained from photoelectrochemical water decomposition.