Photopolymers are optical recording materials appealing for many different applications such as holography, data storage, interconnectors, solar concentrations, or wave-guides fabrication. Recently the capacity of photopolymers to record diffractive optical elements (DOE’s) has been investigated. Different authors have reported proposes to record DOE like fork gratings, photonics structures, le...

We propose a new, to our knowledge, monolithic multilayer optical storage medium in which data may be stored through the diffusional redistribution of fluorescent molecules within a polymer host. The active portion of the medium consists of a photopolymer doped with a fluorescent dye that is polymerized at the focal point of a high-numerical-aperture lens. We believe that as fluorescent molecul...

The performance specifications of a holographic three-dimensional disk system are experimentally characterized. A surface density of 10 bits/µm(2) is experimentally demonstrated with a 100-µm-thick photopolymer as the recording medium.

A general strategy for characterizing the reaction/diffusion kinetics of photopolymer media is proposed, in which key processes are decoupled and independently measured. This strategy enables prediction of a material’s potential refractive index change, solely on the basis of its chemical components. The degree to which a material does not reach this potential reveals the fraction of monomer th...

Photoinitiated silane-ene chemistry has the potential to pave the way toward spatially resolved organosilicon compounds, which might find application in biomedicine, microelectronics, and other advanced fields. Moreover, this approach could serve as a viable alternative to the popular photoinitiated thiol-ene chemistry, which gives access to defined and functional photopolymer networks. A difun...

Photopolymers are very interesting as optically sensitive recording media due to the fact that they are inexpensive, self-processing materials with the ability to capture low-loss, high-fidelity volume recordings of 3D illuminating patterns. We have prepared this paper in part in order to enable the recognition of outstanding issues, which limit in particular the data storage capacity in hologr...

For the first time to our knowledge, a detailed theoretical basis is provided for the well-known inverse-square scaling law of holographic diffraction, which states that replay diffraction efficiency eta = gamma/M2, where M is the number of gratings stored and gamma is a constant system parameter. This law is shown to hold for photopolymer recording media governed by the predictions of the nonl...

The variation in transmittance produced when a photopolymer is irradiated with a pulsed laser is analyzed and experimental results obtained when diffraction gratings are stored using pulsed exposure are presented. In either case, the influence of the energy of the irradiation pulse, the number of pulses, and the pulse repetition rate were studied. The photopolymer used was an acrylamide/polyvin...