1. Production of polycarbonate Polycarbonate (PC) is an amorphous, thermoplastic and transparent plastic. Current annual production of polycarbonates amounts to two million tons worldwide and expected to increase about 5-10% annually (Ref [1],[2]). At present, PC is made mainly by a phosgene-based technique. Phosgene is highly toxic and considered a serious pollutant. DMC can provide an environ...

The widespread application of thermoplastic polymers in different aspects of industries has motivated researchers and companies to improve and upgrade their forming, joining and assembling processes to overcome their limitations. One of the newest joining methods of thermoplastics is friction stir welding which is based on frictional heat generated through contact between a rotating tool and th...

Mechanofluorescent polymer probes were used to visualize stresses and bond scission in polystyrene polycarbonate. Sonication of with a molar mass 1.1 × 105 g·mol–1 solution resulted 30% activation after 1 h, while shorter showed lower percentages. Single-asperity sliding friction tests performed on mechanophore-containing polycarbonate films. Polystyrene clearly visible crack formation correlat...

This paper presents an effective technique to fabricate thermoplastic nanocomposites with high loading of well-dispersed single-walled carbon nanotubes (SWNTs). SWNT membranes were made from a multi-step dispersion and filtration method, and then impregnated with polycarbonate solution to make thermoplastic nanocomposites. High loading of nanotubes was achieved by controlling the viscosity of p...

Unstabilised bisphenol A polycarbonate samples were aged under UV radiation for periods of up to 3000 hours. The samples were then characterised using FTIR/ATR, GPC, SEM, microscopy, light transmission and colour changes. The changes in optical properties were related back to the changes in the polymer microstructure and composition. In this study, the molecular weight of polycarbonate was seen...

A series of CoIII carboxylate based upon N,N,O,O-tetradentate Schiff base ligand framework have been prepared. X-ray diffraction analysis confirms that these Schiff base CoIII carboxylate are all monomeric species with a six-coordinated central Co in their solid structures. The activities and polycarbonate selectivity of these complexes toward the copolymerization of epoxide (cyclohexene oxide ...

Polycarbonate membrane filters were used to concentrate 916 sputum specimens for detecting acid-fast bacilli by microscopic examination. These results were compared with those of smears prepared from centrifugates and direct smears of the same specimens. Culture isolation, the control procedure, demonstrated the presence of acid-fast bacilli in 76 specimens. The number of positive specimens det...

The covalent functionalization of exfoliated hexagonal boron nitride (h-BN) nanosheets by nitrene addition is described. Integration of functionalized h-BN nanosheets within a polycarbonate matrix is demonstrated and was found to afford significant increases in mechanical properties. This integration methodology was further extended by the covalent modification of the h-BN nanosheets with polym...