Postsynthetic modification can be used to introduce sulfonamide functionalities into MOF frameworks. Using sulfonyl chlorides as reactive intermediates, Cr-MIL-SO3H and CAU-1-NH2 have been further modified to give hitherto unknown functionalized MOFs in which a sulfonamide group is bound to the framework either by its N or its S atom.

The asymmetric unit of the title co-crystal, C12H14N4O2S·0.5C6H12N2, comprises the sulfonamide mol-ecule and half a mol-ecule of 1,4-di-aza-bicyclo-[2.2.2]octane (DABCO), the latter being disposed about a crystallographic twofold rotation axis. In the sulfonamide mol-ecule, the aromatic rings are almost perpendicular to one another [dihedral angle = 75.01 (8)°]. In the crystal, mol-ecules are c...

The title mol-ecule, C(11)H(15)N(3)O(2)S, features a five-membered ring which is twisted about the middle CH(2)-CH(2) bond. The benzene ring is inclined with respect to the imine residue [C-N-N-C torsion angle = 165.4 (2)°]. Supra-molecular layers in the bc plane are formed by hydrogen bonds between the amine H atoms and sulfonamide O and imine N atoms, as well as by a weak hydrazine H-atom int...

The molecule of the title compound, C(24)H(36)N(2)O(2)S, displays a U-shaped conformation. The prominent inter-molecular inter-actions are N-H⋯O hydrogen bonds, resulting in the formation of dimers. Additional C-H⋯π contacts involving one of the methyl-ene groups of the macrocycle and the naphthalene rings of a neighbouring mol-ecule stabilize the packing structure. In the crystal structure, th...

The structure of the title compound, C(19)H(20)N(2)O(2)S, displays inter-molecular N-H⋯O hydrogen bonding, which generates inversion dimers. There is no π-π stacking in the crystal structure. The dihedral angle between the phenyl ring and naphthalene ring system is 59.16 (11)°.

The title compound, C(15)H(21)N(3)O(3)S, is known to be an impurity of gliclazide [systematic name: N-(hexa-hydro-1H-cyclopenta[c]pyrrol-2-ylcarbamo-yl)-4-methyl-benzene-sulfonamide], a sul-fonyl-urea anti-diabetic drug. Gliclazide has a p-tolyl group substituting the sulfonamide functionality, while the title mol-ecule contains an o-tolyl group. Both five-membered fused rings adopt envelope co...

In the title compound, C(21)H(23)NO(4)S, the dihedral angle between the naphthalene residue and the benzene ring is 7.66 (3)°. In the molecule, there are some short C-H⋯O interactions. In the crystal, the structure is stabilized by weak intra-molecular C-H⋯O hydrogen bonds and the crystal structure is stabilized by weak C-H⋯O, C-H⋯π and π-π [centroid-centroid distance = 3.710 (2) Å] inter-actions.

The crystal structure of the title compound, [Ru(C(10)H(15))(C(7)H(9)NO(2)S)]C(24)H(20)B, has been determined as part of our investigation into the structural and biological properties of organometallic Ru(II)-arene-Cp* complex salts of the type [R-PhRuCp*](+)·X(-) (where Cp* is penta-methyl-cyclo-penta-diene). Tethering the RuCp* group to the benzene ring of p-toluene-sulfonamide results in on...