Polymer-nanoparticle composites (PNCs) play an increasing role in technology. Inorganic or organic nanoparticles are usually incorporated into a polymer matrix to improve material properties. Polyurea is a spontaneously occurring PNC, exhibiting a phase segregated structure with hard nanodomains embedded in a soft (elastically compliant) matrix. This system shows two glass transitions at Tg1 an...

We leverage the phase segregated microstructure of polyurea to study its shock response using molecular dynamics (MD) simulation. The two domains, hard and soft are investigated separately. domains is studied a multiscale shock-simulation approach that allows simulation low pressure shocks. Both exhibit an unconventional behavior at velocities typically associated with polymers. domain marked b...

Cinnamic acid derivatives bearing a nitroxyl moiety (2,2,6,6-tetramethyl-1-oxyl-4-piperidyl 3-E-aryl acrylates) were synthesized in 30-100% yield using a Mizoroki-Heck cross-coupling reaction between 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl and iodobenzene derivatives in the presence of palladium(II) acetate coordinated with a tri(o-tolyl)phosphine ligand immobilized in a polyurea mat...

BACKGROUND Aerogels are a versatile group of nanostructured/nanoporous materials with physical and chemical properties that can be adjusted to suit the application of interest. In terms of biomedical applications, aerogels are particularly suitable for implants such as membranes, tissue growth scaffolds, and nerve regeneration and guidance inserts. The mesoporous nature of aerogels can also be ...

Polyurethane–polyurea hybrid nanocapsules can be used as efficient delivery systems of anticancer Ir( iii ) metallodrugs.

A photolabile ruthenium-based complex, [Ru(bpy)2 (4AMP)2 ](PF6 )2 , (4AMP=4-(aminomethyl)pyridine) is incorporated into polyurea organo- and hydrogels via the reactive amine moieties on the photocleavable 4AMP ligands. While showing long-term stability in the dark, cleavage of the pyridine-ruthenium bond upon irradiation with visible or near-infrared irradiation (in a two-photon process) leads ...

The strain rate sensitivity of polyurea is characterized using a modified split Hopkinson pressure bar (SHPB) system. The device is composed of a hydraulic piston along with nylon input and output bars. In combination with an advanced wave deconvolution method, the modified SHPB system provides an unlimited measurement time and thus can be used to perform experiments at low, intermediate and hi...