The linear viscoelastic behavior of thermoplastic hybrid inorganic-organic polymers synthesized through radical copolymerization of styrene and styryl-based polyhedral oligosilsesquioxane (POSS), R7(Si8O12) (C6H4CHdCH2), with R ) isobutyl (iBu), cyclopentyl (Cp), and cyclohexyl (Cy), was studied to reveal a significant influence of the vertex group, R. The glass transition temperatures were fou...

The study was conducted to evaluate the cytocompatibility and hydrolytic degradability of the new poly(lactic acid)/polyethylene glycol-polyhedral oligomeric silsesquioxane (peg-POSS/PLLA) nanocomposite as potential material for cartilage regeneration. PLLA scaffolds containing 0 to 5% of peg-POSS were fabricated by electrospinning. Human mesenchymal stem cells (hMSC's) were cultured in vitro t...

We present a DSC and X-ray scattering study investigating the effect of polyhedral oligomeric silsesquioxane (POSS) block crystallinity on self-assembly poly(acryloisobutyl silsesquioxane)-b-poly(ethylene oxide)-b-poly(acryloisobutyl silsesquioxane) (POSS-PEO-POSS) triblock copolymer poly(ethylene oxide)-b- (PEO-POSS) diblock copolymers mixed with lithium bis(trifluoromethanesulfonyl)imide salt...

Thermally stable dual emission followed by white-light luminescence from hybrid materials is reported. Hybrid films were prepared with a spin-coating method the mixture solution containing tetraphenylethene (TPE)-integrated polyhedral oligomeric silsesquioxane (POSS) and poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylene vinylene] (MEH-PPV). TPE-tethered POSS (TPE-POSS) showed high compatibility...

The electronic properties of polyhedral oligomeric silsesquioxanes (POSS) have recently been subjected to study. Although theoretical calculations have predicted that POSS can work as an acceptor for π-conjugated organic units, an effective reaction to incorporate aryl groups into a POSS backbone remains to be established. In this work, Rh-catalyzed direct arylation has been developed. Heptaiso...

A broadband cholesteric liquid crystal (CLC) device with a multi-domain structure is demonstrated by using an aggregation of polyhedral oligomeric silsesquioxane (POSS) nanoparticles in the CLC layer. The aggregation pattern of the self-assembled POSS nanoparticles depends on the concentration of POSS doped in the mixture of POSS/CLC and the cooling rate of the mixture from a temperature higher...

The dispersal, quiescent crystallization kinetics and morphology of a series of unique polyethylene ‒polyhedral oligomeric silsesquioxanes (PE-POSS) nanocomposite blends is presented. POSS molecules with long linear alkyl-chain substituents were blended at one composition into a commercial low density polyethylene. Time-resolved Smalland WideAngle X-Ray scattering (SAXS/WAXS) and thermal techni...

Polyhedral oligomeric silsesquioxane (POSS) based materials are a class of organic/inorganic hybrid nanomaterials with many interesting properties. Recent experiments have demonstrated that self-assembly of tethered POSS nanocubes is a promising route to the synthesis of novel materials with highly ordered, complex nanostructures. Using a coarsegrained model developed for tethered POSS, we perf...

PIM-1 mixed matrix membranes (MMMs) were fabricated with polyhedral oligomeric silsesquioxane (POSS) and graphene oxide (GO) functionalized POSS (GO-POSS), tested for CO2/N2 (single gas) CO2/CH4 (1:1, v:v gas mixture). The CO2 permeability of the best performing fresh MMM (containing 0.05 wt% GO-POSS) was ? 12000 Barrer, which is 69% higher than that neat membrane, about same selectivity (CO2/C...